TY  - JOUR
AB  - In this paper, we report on a novel design strategy of an efficient sorbent for removal of trace contaminants from water. This kind of sorbent is composed of a nonporous core of SiO2 nanofiber and a mesoporous shell (denoted as nSiO2@mSiO2 (" n" means " nonporous" and " m" means " mesoporous" )). The nSiO2@mSiO2 fiber possesses a continuously long fibrous shape and mesoporous micromorphology, thus, showing both high sorption capacity and separability. The flexible nonporous SiO2 nanofiber was prepared with electrospinning first, followed by covering a mesoporous SiO2 shell based on a modified Stöber method using CTAB (cetyltrimethylammonium bromide) as the directing agent for formation of the mesopores. Also, functional thiol groups were grafted on the nSiO2@mSiO2 to enhance its performance. With a large specific surface area and long fibrous morphology, the nSiO2@mSiO2 fiber and its thiol-functionalized counterpart exhibit impressive performance on removal of Pb2+ and Cd2+ from water. Furthermore, the flexible texture and fibrous morphology of the nSiO2@mSiO2 fiber also made the removal of metal ions and the separation process more convenient and efficient, implying that the nSiO2@mSiO2 fiber could have great potential for industrial applications. © 2011 Elsevier Inc.
AU  - Ma, Z
AU  - Ji, H
AU  - Teng, Y
AU  - Dong, G
AU  - Zhou, J
AU  - Tan, D
AU  - Qiu, J
DA  - 2011/06/15
DO  - 10.1016/j.jcis.2011.02.066
EP  - 553
JO  - Journal of Colloid and Interface Science
PY  - 2011/06/15
SP  - 547
TI  - Engineering and optimization of nano- and mesoporous silica fibers using sol-gel and electrospinning techniques for sorption of heavy metal ions
VL  - 358
Y1  - 2011/06/15
Y2  - 2026/07/09
ER  -