Prediction and structure of polymorphic lattice inclusion compounds of 2,7-dimethyltricyclo[4.3.1.0<sup>3,8</sup>]undecane-syn-2,syn-7-diol

Ung, AT; Bishop, R; Craig, DC; Dance, IG; Scudder, ML

Prediction and structure of polymorphic lattice inclusion compounds of 2,7-dimethyltricyclo[4.3.1.0<sup>3,8</sup>]undecane-syn-2,syn-7-diol

Ung, AT

Bishop, R Craig, DC Dance, IG Scudder, ML

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Publication Type:: Journal Article
Citation:: Tetrahedron, 1993, 49 (3), pp. 639 - 648
Issue Date:: 1993-01-15

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Field	Value	Language
dc.contributor.author	Ung, AT https://orcid.org/0000-0002-5665-0702	en_US
dc.contributor.author	Bishop, R	en_US
dc.contributor.author	Craig, DC	en_US
dc.contributor.author	Dance, IG	en_US
dc.contributor.author	Scudder, ML	en_US
dc.date.issued	1993-01-15	en_US
dc.identifier.citation	Tetrahedron, 1993, 49 (3), pp. 639 - 648	en_US
dc.identifier.issn	0040-4020	en_US
dc.identifier.uri	http://hdl.handle.net/10453/8418
dc.description.abstract	The host molecule 2,7-dimethyltricyclo[4.3.1.03,8]undecane-syn-2,syn-7-diol 1 is known to form two different structural types of lattice inclusion compound dependent on the guest molecule chosen. Guests, including 1,2-dichlorobenzene 2, have now been predicted which result in the formation of both lattice types according to the crystallisation conditions employed. Crystal structures of the ellipsoidal clathrate type: (Racemic-1)4.(1,2-Dichlorobenzene), space group I41/acd; and the helical tubulate type: (Resolved-1)3.(1,2-Dichlorobenzene), space group P3121 are presented. The latter polymorph is transformed into the former on heating in a sealed system. © 1993.	en_US
dc.relation.ispartof	Tetrahedron	en_US
dc.relation.isbasedon	10.1016/S0040-4020(01)86266-9	en_US
dc.subject.classification	Organic Chemistry	en_US
dc.title	Prediction and structure of polymorphic lattice inclusion compounds of 2,7-dimethyltricyclo[4.3.1.0<sup>3,8</sup>]undecane-syn-2,syn-7-diol	en_US
dc.type	Journal Article
utslib.citation.volume	3	en_US
utslib.citation.volume	49	en_US
utslib.for	060702 Plant Cell and Molecular Biology	en_US
utslib.for	030402 Biomolecular Modelling and Design	en_US
utslib.for	0304 Medicinal and Biomolecular Chemistry	en_US
utslib.for	0305 Organic Chemistry	en_US
pubs.embargo.period	Not known	en_US
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
pubs.organisational-group	/University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
pubs.organisational-group	/University of Technology Sydney/Strength - CCET - Centre for Clean Energy Technology
utslib.copyright.status	closed_access
pubs.issue	3	en_US
pubs.publication-status	Published	en_US
pubs.volume	49	en_US

Abstract:

The host molecule 2,7-dimethyltricyclo[4.3.1.03,8]undecane-syn-2,syn-7-diol 1 is known to form two different structural types of lattice inclusion compound dependent on the guest molecule chosen. Guests, including 1,2-dichlorobenzene 2, have now been predicted which result in the formation of both lattice types according to the crystallisation conditions employed. Crystal structures of the ellipsoidal clathrate type: (Racemic-1)4.(1,2-Dichlorobenzene), space group I41/acd; and the helical tubulate type: (Resolved-1)3.(1,2-Dichlorobenzene), space group P3121 are presented. The latter polymorph is transformed into the former on heating in a sealed system. © 1993.

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