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Zhang, Guojin 2022-10-04T03:29:33Z 2022-10-04T03:29:33Z 2022 http://hdl.handle.net/10453/162287 University of Technology Sydney. Faculty of Engineering and Information Technology. Hydrogen-rich compounds containing boron (B), nitrogen (N), and carbon (C) have attracted wide research attention for hydrogen storage. Borane-amine complexes are among the most promising candidates, but so far all the reported systems have various drawbacks. This PhD project invented a novel hydrogen delivery system employing borane-amine complexes and organic amines, which demonstrated a high hydrogen capacity and favourable dehydrogenation and regeneration performance. A typical setup involves ethylenediamine bisborane (EDAB) and ethylenediamine (ED), catalysed by Pt/C, producing six equivalents of hydrogen gas per equivalent of EDAB in less than ten minutes at room temperature. After releasing hydrogen gas, the dehydrogenation product was successfully regenerated at room temperature. Thesis (PhD) en_US https://opus.lib.uts.edu.au/bitstream/10453/162287/2/02whole.pdf The author owns the copyright in this thesis including all reproduction and reuse rights for the work. The work may not be altered without the permission of the copyright owner. Attribution is essential when quoting or paraphrasing from this thesis. info:eu-repo/semantics/embargoedAccess au.edu.uts.lib/ppc © 2022 Guojin Zhang Synthesis and Applications of Boron-Carbon-Nitrogen Containing H-rich Compounds as Hydrogen Carriers Thesis open_access 2026-08-01T00:00:00+1000