X-ray mapping and scatter diagram analysis of the discoloring products resulting from the interaction of artist's pigments

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dc.contributor.author White, R
dc.contributor.author Thomas, P
dc.contributor.author Phillips, MR
dc.contributor.author Moran, K
dc.contributor.author Wuhrer, R
dc.date.accessioned 2011-02-07T06:18:28Z
dc.date.issued 2010-10
dc.date.issued 2010-10
dc.identifier.citation Microscopy and Microanalysis, 2010, 16 (5), pp. 594 - 598
dc.identifier.citation Microscopy and Microanalysis, 2010, 16 (5), pp. 594 - 598
dc.identifier.issn 1431-9276
dc.identifier.other C1 en_US
dc.identifier.uri http://hdl.handle.net/10453/13066
dc.description.abstract The discoloring interaction between the artist's pigments cadmium yellow and the copper-containing malachite, an interaction that is conjectured to cause black spotting in oil paintings of the 19th and early 20th centuries, was examined using X-ray mapping and scatter diagram analysis. The application of these coupled techniques confirmed that copper sulfide phases were produced during discoloration reaction. Scatter diagram analysis indicated that two copper sulfide stoichiometries (CuS and Cu3S2) were present as reaction products where previously only crystalline CuS (covellite) had been identified by X-ray diffraction. The results demonstrate the potential of X-ray mapping coupled with scatter diagram analysis for the identification of both crystalline and X-ray amorphous phases produced by such complex heterogeneous interactions and their applicability to the investigation of interactions of artists' pigments. © Microscopy Society of America 2010.
dc.description.abstract The discoloring interaction between the artist's pigments cadmium yellow and the copper-containing malachite, an interaction that is conjectured to cause black spotting in oil paintings of the 19th and early 20th centuries, was examined using X-ray mapping and scatter diagram analysis. The application of these coupled techniques confirmed that copper sulfide phases were produced during discoloration reaction. Scatter diagram analysis indicated that two copper sulfide stoichiometries (CuS and Cu3S2) were present as reaction products where previously only crystalline CuS (covellite) had been identified by X-ray diffraction. The results demonstrate the potential of X-ray mapping coupled with scatter diagram analysis for the identification of both crystalline and X-ray amorphous phases produced by such complex heterogeneous interactions and their applicability to the investigation of interactions of artists' pigments. © Microscopy Society of America 2010.
dc.language eng
dc.language eng
dc.relation.isbasedon 10.1017/S143192761009375X
dc.title X-ray mapping and scatter diagram analysis of the discoloring products resulting from the interaction of artist's pigments
dc.title X-ray mapping and scatter diagram analysis of the discoloring products resulting from the interaction of artist's pigments
dc.type Journal Article
dc.description.version Published
dc.parent Microscopy and Microanalysis
dc.parent Microscopy and Microanalysis
dc.journal.volume 5
dc.journal.volume 16
dc.journal.number 5 en_US
dc.publocation New York en_US
dc.publocation London, UK
dc.identifier.startpage 594 en_US
dc.identifier.endpage 598 en_US
dc.cauo.name SCI.Faculty of Science en_US
dc.conference Verified OK en_US
dc.for 0204 Condensed Matter Physics
dc.personcode 810070
dc.personcode 960405
dc.personcode 880536
dc.percentage 100 en_US
dc.classification.name Condensed Matter Physics en_US
dc.classification.type FOR-08 en_US
dc.edition en_US
dc.edition 1
dc.custom en_US
dc.date.activity en_US
dc.location.activity ISI:000282911600010 en_US
dc.description.keywords artist's pigments
dc.description.keywords artist's pigments
dc.description.keywords cadmium yellow
dc.description.keywords cadmium yellow
dc.description.keywords discoloration
dc.description.keywords discoloration
dc.description.keywords malachite
dc.description.keywords malachite
dc.description.keywords scatter diagram analysis
dc.description.keywords scatter diagram analysis
dc.description.keywords X-ray mapping
dc.description.keywords X-ray mapping
pubs.embargo.period Not known
pubs.organisational-group /University of Technology Sydney
pubs.organisational-group /University of Technology Sydney/Faculty of Science
pubs.organisational-group /University of Technology Sydney/Strength - Built Infrastructure
pubs.organisational-group /University of Technology Sydney/Strength - Built Infrastructure
pubs.organisational-group /University of Technology Sydney/Strength - Management and Organisation Studies
pubs.organisational-group /University of Technology Sydney/Strength - Management and Organisation Studies
pubs.organisational-group /University of Technology Sydney/Strength - Materials and Technology for Energy Efficiency
pubs.organisational-group /University of Technology Sydney/Strength - Materials and Technology for Energy Efficiency
utslib.copyright.status Open Access
utslib.copyright.date 2015-04-15 12:23:47.074767+10
pubs.consider-herdc true
utslib.collection.history School of Chemistry and Forensic Science (ID: 339)
utslib.collection.history General (ID: 2)


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