Synthesis and characterization of SrBi4Ti4O15 ferroelectric filler based composite polymer electrolytes for lithium ion batteries

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dc.contributor.author Shanmukaraj, D
dc.contributor.author Wang, G
dc.contributor.author Liu, HK
dc.contributor.author Murugan, R
dc.date.accessioned 2011-02-07T06:18:48Z
dc.date.issued 2008-01
dc.identifier.citation Polymer Bulletin, 2008, 60 pp. 351 - 361
dc.identifier.issn 0170-0839
dc.identifier.other C1UNSUBMIT en_US
dc.identifier.uri http://hdl.handle.net/10453/13100
dc.description.abstract Composite polymer electrolytes (CPEs) based on poly (ethylene oxide) (PEO) (Mol.Wt ~ 6 x 105) complexed with LiN(CF3SO2)2 lithium salt and SrBi4Ti4O15 ferroelectric ceramic filler have been prepared as films. Citrate gel technique and conventional solid state technique were employed for the synthesis of the ferroelectric fillers in order to study the effect of particle size of the filler on ionic conductivity of the polymer electrolyte. Characterization techniques such as X-ray diffraction (XRD), differential thermal analysis (DTA), scanning electron microscopy (SEM) and temperature dependant DC conductivity studies were taken for the prepared polymer composite electrolytes. The broadening of DTA endotherms on addition of ceramic fillers to the polymer salt complex indicated the reduction in crystallinity. An enhancement in conductivity was observed with the addition of SrBi4Ti4O15 as filler to the (PEO)8-LiN(CF3SO2)2 polymer salt complexes. Among the investigated samples (PEO)8-LiN(CF3SO2)2 +10 wt% SrBi4Ti4O15 (citrate gel) polymer composite exhibits a maximum conductivity.
dc.publisher Springer Berlin
dc.relation.isbasedon 10.1007/s00289-007-0845-y
dc.title Synthesis and characterization of SrBi4Ti4O15 ferroelectric filler based composite polymer electrolytes for lithium ion batteries
dc.type Journal Article
dc.parent Polymer Bulletin
dc.journal.volume 60
dc.publocation Heidelberg en_US
dc.identifier.startpage 351 en_US
dc.identifier.endpage 361 en_US
dc.cauo.name SCI.Faculty of Science en_US
dc.conference Verified OK en_US
dc.for 0303 Macromolecular and Materials Chemistry
dc.personcode 109499
dc.percentage 100 en_US
dc.classification.name Macromolecular and Materials Chemistry en_US
dc.classification.type FOR-08 en_US
dc.edition en_US
dc.custom en_US
dc.date.activity en_US
dc.location.activity en_US
dc.description.keywords NA
dc.description.keywords NA
pubs.embargo.period Not known
pubs.organisational-group /University of Technology Sydney
pubs.organisational-group /University of Technology Sydney/Faculty of Science
pubs.organisational-group /University of Technology Sydney/Strength - Materials and Technology for Energy Efficiency
pubs.organisational-group /University of Technology Sydney/Strength - Materials and Technology for Energy Efficiency
utslib.copyright.status Closed Access
utslib.copyright.date 2015-04-15 12:17:09.805752+10
utslib.copyright.date 2015-04-15 12:17:09.805752+10
pubs.consider-herdc false
pubs.consider-herdc false
utslib.collection.history Closed (ID: 3)
utslib.collection.history School of Chemistry and Forensic Science (ID: 339)


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