Synthesis, electrochemistry and spectroscopic properties of ruthenium phthalocyanine and naphthalocyanine complexes with triphenylarsine ligands

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Show simple item record Rawling, T McDonagh, AM Colbran, SB 2010-05-28T09:43:25Z 2008-01-01
dc.identifier.citation Inorganica Chimica Acta, 2008, 361 (1), pp. 49 - 55
dc.identifier.issn 0020-1693
dc.identifier.other C1 en_US
dc.description.abstract The synthesis, electrochemistry and spectroscopic properties of [PcRu(AsPh3)2] (1) and [{(tBu)4Nc}Ru(AsPh3)2] (2), where Pc = phthalocyanine and Nc = naphthalocyanine are reported. These complexes are the first examples of metal phthalocyanine and naphthalocyanine complexes with axially-coordinated arsine ligands. The AsPh3 ligands readily dissociate in non-coordinating solvents with 2 showing more rapid dissociation. In cyclic voltammetry experiments, 1 displayed three macrocycle-centred redox processes; one reduction and two oxidation processes. One reduction and three oxidation processes were observed for 2. The reduction and first oxidation are assigned to macrocycle-centred processes. The UV-Vis spectra of both complexes recorded over time showed macrocycle-centred oxidation. The oxidation was hindered by removing dioxygen from the solvent or adding excess AsPh3. © 2007 Elsevier B.V. All rights reserved.
dc.language eng
dc.relation.hasversion Accepted manuscript version en_US
dc.relation.isbasedon 10.1016/j.ica.2007.06.043
dc.title Synthesis, electrochemistry and spectroscopic properties of ruthenium phthalocyanine and naphthalocyanine complexes with triphenylarsine ligands
dc.type Journal Article
dc.parent Inorganica Chimica Acta
dc.journal.volume 1
dc.journal.volume 361
dc.journal.number en_US
dc.publocation Amsterdam en_US
dc.identifier.startpage 49 en_US
dc.identifier.endpage 55 en_US SCI.Faculty of Science en_US
dc.conference Verified OK en_US
dc.for 0302 Inorganic Chemistry
dc.personcode 030871
dc.personcode 040731
dc.percentage 100 en_US Inorganic Chemistry en_US
dc.classification.type FOR-08 en_US
dc.edition en_US
dc.custom en_US en_US
dc.location.activity ISI:000253226700008 en_US
dc.description.keywords Arsine
dc.description.keywords Electrochemistry
dc.description.keywords Naphthalocyanine
dc.description.keywords Phthalocyanine
dc.description.keywords Ruthenium
pubs.embargo.period Not known
pubs.organisational-group /University of Technology Sydney
pubs.organisational-group /University of Technology Sydney/Faculty of Science
pubs.organisational-group /University of Technology Sydney/Graduate School of Health
pubs.organisational-group /University of Technology Sydney/Strength - Forensic Science
pubs.organisational-group /University of Technology Sydney/Strength - Materials and Technology for Energy Efficiency
utslib.copyright.status Open Access 2015-04-15 12:23:47.074767+10 2015-04-15 12:23:47.074767+10
pubs.consider-herdc true
utslib.collection.history School of Chemistry and Forensic Science (ID: 339)
utslib.collection.history General (ID: 2)

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