Aluminium triflate catalysed O-glycosidation: temperature-switched selective Ferrier rearrangement or direct addition with alcohols.

Publication Type:
Journal Article
Organic & biomolecular chemistry, 2012, 10 (29), pp. 5636 - 5642
Issue Date:
Full metadata record
Files in This Item:
Filename Description Size
c2ob25540e.pdfPublished Version162.93 kB
Adobe PDF
A temperature-controlled mechanism switch between the Al(OTf)(3)-catalysed direct addition of alcohols or the Ferrier rearrangement reactions in some glycals is presented. The scope and limitations are investigated as are the influence of the stereochemistry and nature of the protecting groups on the glycal substrate.
Please use this identifier to cite or link to this item: