Cooperative ligand effects in phase-switching homogeneous catalysts

Publication Type:
Journal Article
Citation:
Angewandte Chemie - International Edition, 2012, 51 (7), pp. 1648 - 1652
Issue Date:
2012-02-13
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It takes two: Xantphos ligands that contain amidate groups are selective for the linear versus the branched-chain products in the rhodium-catalyzed hydroformylation of 1-octene. However, the catalyst only undergoes CO 2-mediated phase switching in the presence of amidine-substituted triphenylphosphine (see scheme). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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