Cooperative ligand effects in phase-switching homogeneous catalysts

Publication Type:
Journal Article
Angewandte Chemie - International Edition, 2012, 51 (7), pp. 1648 - 1652
Issue Date:
Filename Description Size
Mokhadinyana_et_al-2012-Angewandte_Chemie_(International_ed._in_English).pdfPublished Version565.27 kB
Adobe PDF
Full metadata record
It takes two: Xantphos ligands that contain amidate groups are selective for the linear versus the branched-chain products in the rhodium-catalyzed hydroformylation of 1-octene. However, the catalyst only undergoes CO 2-mediated phase switching in the presence of amidine-substituted triphenylphosphine (see scheme). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Please use this identifier to cite or link to this item: