Cooperative ligand effects in phase-switching homogeneous catalysts

Mokhadinyana, M; Desset, SL; Williams, DBG; Cole-Hamilton, DJ

Cooperative ligand effects in phase-switching homogeneous catalysts

Mokhadinyana, M Desset, SL Williams, DBG

Cole-Hamilton, DJ

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Publication Type:: Journal Article
Citation:: Angewandte Chemie - International Edition, 2012, 51 (7), pp. 1648 - 1652
Issue Date:: 2012-02-13

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Field	Value	Language
dc.contributor.author	Mokhadinyana, M	en_US
dc.contributor.author	Desset, SL	en_US
dc.contributor.author	Williams, DBG https://orcid.org/0000-0002-3703-6301	en_US
dc.contributor.author	Cole-Hamilton, DJ	en_US
dc.date.issued	2012-02-13	en_US
dc.identifier.citation	Angewandte Chemie - International Edition, 2012, 51 (7), pp. 1648 - 1652	en_US
dc.identifier.issn	1433-7851	en_US
dc.identifier.uri	http://hdl.handle.net/10453/115028
dc.description.abstract	It takes two: Xantphos ligands that contain amidate groups are selective for the linear versus the branched-chain products in the rhodium-catalyzed hydroformylation of 1-octene. However, the catalyst only undergoes CO 2-mediated phase switching in the presence of amidine-substituted triphenylphosphine (see scheme). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.	en_US
dc.relation.ispartof	Angewandte Chemie - International Edition	en_US
dc.relation.isbasedon	10.1002/anie.201108200	en_US
dc.subject.classification	Organic Chemistry	en_US
dc.subject.mesh	Rhodium	en_US
dc.subject.mesh	Aldehydes	en_US
dc.subject.mesh	Alkenes	en_US
dc.subject.mesh	Organometallic Compounds	en_US
dc.subject.mesh	Ligands	en_US
dc.subject.mesh	Molecular Structure	en_US
dc.subject.mesh	Catalysis	en_US
dc.title	Cooperative ligand effects in phase-switching homogeneous catalysts	en_US
dc.type	Journal Article
utslib.citation.volume	7	en_US
utslib.citation.volume	51	en_US
utslib.for	0303 Macromolecular and Materials Chemistry	en_US
utslib.for	03 Chemical Sciences	en_US
pubs.embargo.period	Not known	en_US
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
utslib.copyright.status	closed_access
pubs.issue	7	en_US
pubs.publication-status	Published	en_US
pubs.volume	51	en_US

Abstract:

It takes two: Xantphos ligands that contain amidate groups are selective for the linear versus the branched-chain products in the rhodium-catalyzed hydroformylation of 1-octene. However, the catalyst only undergoes CO 2-mediated phase switching in the presence of amidine-substituted triphenylphosphine (see scheme). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Please use this identifier to cite or link to this item:

http://hdl.handle.net/10453/115028