The synthesis of planar chiral pseudo-gem aminophosphine pre-ligands based on [2.2]paracyclophane

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Journal Article
Organic and Biomolecular Chemistry, 2017, 15 (42), pp. 8975 - 8984
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© 2017 The Royal Society of Chemistry. The synthesis of three planar chiral pseudo-gem disubstituted [2.2]paracyclophane-derived P,N-pre-ligands is reported along with preliminary results of their activity in the amination of aryl bromides and chlorides. The pseudo-gem aminophosphines were capable of mediating the coupling reaction at a loading of 1 mol%.
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