Regeneration Of Aromatic Carbonyl Compounds From The Corresponding Oximes Using Tetrapyridine Silver(Ii) Peroxydisulfate In Acetonitrile And Aqueous Media

Publisher:
Taylor & Francis Inc
Publication Type:
Journal Article
Citation:
Synthetic Communications, 2010, 40 (5), pp. 725 - 731
Issue Date:
2010-01
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The results of the recovery of both aldehyde and ketone carbonyl functionalities from the oxime derivatives in aromatic carbonyl compounds using tetrapyridine silver(II) peroxydisulfate [Ag(py)4S2O8] as a stable, mild, and efficient oxidizing agent is reported. Yields in excess of 85% were achieved at room temperature in both acetonitrile and aqueous media, making the method versatile and suitable for a wide range of aromatic carbonyl oximes.
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