Regeneration of aromatic carbonyl compounds from the corresponding oximes using tetrapyridine silver(II) peroxydisulfate in acetonitrile and aqueous media

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Journal Article
Synthetic Communications, 2010, 40 (5), pp. 725 - 731
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The results of the recovery of both aldehyde and ketone carbonyl functionalities from the oxime derivatives in aromatic carbonyl compounds using tetrapyridine silver(II) peroxydisulfate [Ag(py)4S2O 8] as a stable, mild, and efficient oxidizing agent is reported. Yields in excess of 85% were achieved at room temperature in both acetonitrile and aqueous media, making the method versatile and suitable for a wide range of aromatic carbonyl oximes.
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