Bis(κ<sup>2</sup>S,S′-di(isopropyl)dithiocarbamato)nickel(II): Anagostic C-H⋯Ni interactions and physical properties

Angeloski, A; Baker, AT; Bhadbhade, M; McDonagh, AM

Bis(κ<sup>2</sup>S,S′-di(isopropyl)dithiocarbamato)nickel(II): Anagostic C-H⋯Ni interactions and physical properties

Angeloski, A

Baker, AT

Bhadbhade, M McDonagh, AM

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Publication Type:: Journal Article
Citation:: Journal of Molecular Structure, 2016, 1113 pp. 127 - 132
Issue Date:: 2016-06-05

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Field	Value	Language
dc.contributor.author	Angeloski, A https://orcid.org/0000-0003-4395-1829	en_US
dc.contributor.author	Baker, AT https://orcid.org/0000-0001-9700-0178	en_US
dc.contributor.author	Bhadbhade, M	en_US
dc.contributor.author	McDonagh, AM https://orcid.org/0000-0002-9502-1175	en_US
dc.date.available	2020-05-25T19:09:52Z
dc.date.issued	2016-06-05	en_US
dc.identifier.citation	Journal of Molecular Structure, 2016, 1113 pp. 127 - 132	en_US
dc.identifier.issn	0022-2860	en_US
dc.identifier.uri	http://hdl.handle.net/10453/43444
dc.description.abstract	© 2016 Elsevier B.V. All rights reserved. The molecular structure of bis(κ2S,S′-di(isopropyl)dithiocarbamato)nickel(II) has been examined by single crystal X-ray diffraction. The data reveal a C-H·Ni anagostic interaction arising from the interaction of two non-equivalent molecules within the crystal. Thermal analysis data show that the complex decomposes at ∼330 °C. The structure of the resultant NiS material was examined using scanning electron microscopy and energy dispersive X-ray spectroscopy which revealed NiS nanowires.	en_US
dc.relation.ispartof	Journal of Molecular Structure	en_US
dc.relation.isbasedon	10.1016/j.molstruc.2016.02.028	en_US
dc.subject.classification	Inorganic & Nuclear Chemistry	en_US
dc.title	Bis(κ<sup>2</sup>S,S′-di(isopropyl)dithiocarbamato)nickel(II): Anagostic C-H⋯Ni interactions and physical properties	en_US
dc.type	Journal Article
utslib.citation.volume	1113	en_US
utslib.for	0306 Physical Chemistry (incl. Structural)	en_US
utslib.for	0307 Theoretical and Computational Chemistry	en_US
pubs.embargo.period	Not known	en_US
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
pubs.organisational-group	/University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
pubs.organisational-group	/University of Technology Sydney/Strength - CCET - Centre for Clean Energy Technology
utslib.copyright.status	open_access
pubs.publication-status	Published	en_US
pubs.volume	1113	en_US

Abstract:

© 2016 Elsevier B.V. All rights reserved. The molecular structure of bis(κ2S,S′-di(isopropyl)dithiocarbamato)nickel(II) has been examined by single crystal X-ray diffraction. The data reveal a C-H·Ni anagostic interaction arising from the interaction of two non-equivalent molecules within the crystal. Thermal analysis data show that the complex decomposes at ∼330 °C. The structure of the resultant NiS material was examined using scanning electron microscopy and energy dispersive X-ray spectroscopy which revealed NiS nanowires.

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http://hdl.handle.net/10453/43443