Two novel 2D metal-organic frameworks based on biphenyl-2,2′,6, 6′-tetracarboxylic acid: Synthesis, structures and luminescent properties

Yang, Z; Liu, J; Liang, XQ; Jiang, Y; Zhang, T; Han, B; Sun, FX; Liu, L

Two novel 2D metal-organic frameworks based on biphenyl-2,2′,6, 6′-tetracarboxylic acid: Synthesis, structures and luminescent properties

Yang, Z Liu, J Liang, XQ Jiang, Y Zhang, T

Han, B Sun, FX Liu, L

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Publication Type:: Journal Article
Citation:: Inorganic Chemistry Communications, 2012, 16 pp. 92 - 94
Issue Date:: 2012-02-01

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Field	Value	Language
dc.contributor.author	Yang, Z	en_US
dc.contributor.author	Liu, J	en_US
dc.contributor.author	Liang, XQ	en_US
dc.contributor.author	Jiang, Y	en_US
dc.contributor.author	Zhang, T https://orcid.org/0000-0001-6436-125X	en_US
dc.contributor.author	Han, B	en_US
dc.contributor.author	Sun, FX	en_US
dc.contributor.author	Liu, L	en_US
dc.date.issued	2012-02-01	en_US
dc.identifier.citation	Inorganic Chemistry Communications, 2012, 16 pp. 92 - 94	en_US
dc.identifier.issn	1387-7003	en_US
dc.identifier.uri	http://hdl.handle.net/10453/114804
dc.description.abstract	Two novel metal-organic frameworks (MOFs) assembled from H 4BPTC, {[Co 2(BPTC)(H 2O) 4(DMF) 2]2H 2O} 1, {[Mn 2(BPTC)(H 2O) 4(DMF) 2]2H 2O} 2, (H 4BPTC = biphenyl-2,2′,6, 6′-tetracarboxylic acid, DMF = N,N-dimethylformamide) have been obtained under hydrothermal conditions, and structurally characterized by single-crystal X-ray diffraction. The results reveal that compounds 1 and 2 are isostructural except the different metal centers, exhibiting a 2D layer structure with 4-4 net. 1 and 2 are also characterized by elemental analysis, IR spectra, TGA analysis and PXRD. The luminescent properties of 1 and 2 in solid state are discussed. © 2011 Elsevier B.V. All rights reserved.	en_US
dc.relation.ispartof	Inorganic Chemistry Communications	en_US
dc.relation.isbasedon	10.1016/j.inoche.2011.12.003	en_US
dc.subject.classification	Inorganic & Nuclear Chemistry	en_US
dc.title	Two novel 2D metal-organic frameworks based on biphenyl-2,2′,6, 6′-tetracarboxylic acid: Synthesis, structures and luminescent properties	en_US
dc.type	Journal Article
utslib.citation.volume	16	en_US
utslib.for	0302 Inorganic Chemistry	en_US
utslib.for	0399 Other Chemical Sciences	en_US
pubs.embargo.period	Not known	en_US
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Engineering and Information Technology
pubs.organisational-group	/University of Technology Sydney/Faculty of Engineering and Information Technology/School of Electrical and Data Engineering
pubs.organisational-group	/University of Technology Sydney/Strength - GBDTC - Global Big Data Technologies
utslib.copyright.status	closed_access
pubs.publication-status	Published	en_US
pubs.volume	16	en_US

Abstract:

Two novel metal-organic frameworks (MOFs) assembled from H 4BPTC, {[Co 2(BPTC)(H 2O) 4(DMF) 2]2H 2O} 1, {[Mn 2(BPTC)(H 2O) 4(DMF) 2]2H 2O} 2, (H 4BPTC = biphenyl-2,2′,6, 6′-tetracarboxylic acid, DMF = N,N-dimethylformamide) have been obtained under hydrothermal conditions, and structurally characterized by single-crystal X-ray diffraction. The results reveal that compounds 1 and 2 are isostructural except the different metal centers, exhibiting a 2D layer structure with 4-4 net. 1 and 2 are also characterized by elemental analysis, IR spectra, TGA analysis and PXRD. The luminescent properties of 1 and 2 in solid state are discussed. © 2011 Elsevier B.V. All rights reserved.

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