Fabrication and characterization of Ni-Ce-Zr ternary disk-shaped catalyst and its application for low-temperature CO2 methanation

Moon, DH; Chung, WJ; Chang, SW; Lee, SM; Kim, SS; Jeung, JH; Ro, YH; Ahn, JY; Guo, W; Ngo, HH; Nguyen, DD

Fabrication and characterization of Ni-Ce-Zr ternary disk-shaped catalyst and its application for low-temperature CO2 methanation

Moon, DH Chung, WJ Chang, SW Lee, SM Kim, SS Jeung, JH Ro, YH Ahn, JY Guo, W

Ngo, HH Nguyen, DD

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Publisher:: ELSEVIER SCI LTD
Publication Type:: Journal Article
Citation:: Fuel, 2020, 260
Issue Date:: 2020-01-15

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Field	Value	Language
dc.contributor.author	Moon, DH
dc.contributor.author	Chung, WJ
dc.contributor.author	Chang, SW
dc.contributor.author	Lee, SM
dc.contributor.author	Kim, SS
dc.contributor.author	Jeung, JH
dc.contributor.author	Ro, YH
dc.contributor.author	Ahn, JY
dc.contributor.author	Guo, W https://orcid.org/0000-0001-5542-2858
dc.contributor.author	Ngo, HH
dc.contributor.author	Nguyen, DD
dc.date.accessioned	2020-07-18T07:40:55Z
dc.date.available	2020-07-18T07:40:55Z
dc.date.issued	2020-01-15
dc.identifier.citation	Fuel, 2020, 260
dc.identifier.issn	0016-2361
dc.identifier.issn	1873-7153
dc.identifier.uri	http://hdl.handle.net/10453/141794
dc.description.abstract	© 2019 Elsevier Ltd This study optimized a Ni-Ce-Zr catalyst and its contents for a CO2 methanation reaction by selecting a disk shape with a high mechanical strength, good durability, and thermal emission resistance. The physical and chemical properties of the obtained catalysts were determined by X-ray diffraction, scanning electron microscopy, Brunauer–Emmett–Teller, hydrogen temperature-programmed reduction, and temperature-programmed desorption of CO2 analyses. In addition, the activity and stability of the obtained catalysts were then evaluated and compared. It was determined that the combined Ni-Ce-Zr catalyst positively affects the conversion of CO2 to CH4. Furthermore, a CO2 methanation experiment was performed under atmospheric pressure conditions at 200–350 °C. The CO2 conversion was 82% at 300 °C, and the CH4 selectivity was 100%. A durability test revealed a difference in the conversion of approximately 6% for 1000 h, which indicates that the catalytic performance was maintained for a significant period.
dc.language	English
dc.publisher	ELSEVIER SCI LTD
dc.relation.ispartof	Fuel
dc.relation.isbasedon	10.1016/j.fuel.2019.116260
dc.rights	info:eu-repo/semantics/openAccess
dc.subject	0306 Physical Chemistry (incl. Structural), 0904 Chemical Engineering, 0913 Mechanical Engineering
dc.subject.classification	Energy
dc.title	Fabrication and characterization of Ni-Ce-Zr ternary disk-shaped catalyst and its application for low-temperature CO2 methanation
dc.type	Journal Article
utslib.citation.volume	260
utslib.for	0306 Physical Chemistry (incl. Structural)
utslib.for	0904 Chemical Engineering
utslib.for	0913 Mechanical Engineering
pubs.organisational-group	/University of Technology Sydney/Faculty of Engineering and Information Technology
pubs.organisational-group	/University of Technology Sydney/Strength - CTWW - Centre for Technology in Water and Wastewater Treatment
pubs.organisational-group	/University of Technology Sydney/Faculty of Engineering and Information Technology/School of Civil and Environmental Engineering
pubs.organisational-group	/University of Technology Sydney
utslib.copyright.status	open_access	*
dc.date.updated	2020-07-18T07:40:47Z
pubs.publication-status	Published
pubs.volume	260

Abstract:

© 2019 Elsevier Ltd This study optimized a Ni-Ce-Zr catalyst and its contents for a CO2 methanation reaction by selecting a disk shape with a high mechanical strength, good durability, and thermal emission resistance. The physical and chemical properties of the obtained catalysts were determined by X-ray diffraction, scanning electron microscopy, Brunauer–Emmett–Teller, hydrogen temperature-programmed reduction, and temperature-programmed desorption of CO2 analyses. In addition, the activity and stability of the obtained catalysts were then evaluated and compared. It was determined that the combined Ni-Ce-Zr catalyst positively affects the conversion of CO2 to CH4. Furthermore, a CO2 methanation experiment was performed under atmospheric pressure conditions at 200–350 °C. The CO2 conversion was 82% at 300 °C, and the CH4 selectivity was 100%. A durability test revealed a difference in the conversion of approximately 6% for 1000 h, which indicates that the catalytic performance was maintained for a significant period.

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http://hdl.handle.net/10453/141794