Fenton-Chemistry-Mediated Radical Polymerization.
- Publisher:
- WILEY-V C H VERLAG GMBH
- Publication Type:
- Journal Article
- Citation:
- Macromolecular rapid communications, 2019, 40, (18), pp. e1900220
- Issue Date:
- 2019-09
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Fenton-Chemistry-Mediated Radical Polymerization.pdf | 4.38 MB | Adobe PDF |
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Full metadata record
Field | Value | Language |
---|---|---|
dc.contributor.author | Reyhani, A | |
dc.contributor.author | McKenzie, TG | |
dc.contributor.author |
Fu, Q https://orcid.org/0000-0002-4012-330X |
|
dc.contributor.author | Qiao, GG | |
dc.date.accessioned | 2021-03-30T23:12:03Z | |
dc.date.available | 2021-03-30T23:12:03Z | |
dc.date.issued | 2019-09 | |
dc.identifier.citation | Macromolecular rapid communications, 2019, 40, (18), pp. e1900220 | |
dc.identifier.issn | 1022-1336 | |
dc.identifier.issn | 1521-3927 | |
dc.identifier.uri | http://hdl.handle.net/10453/147694 | |
dc.description.abstract | In this review, the power of a classical chemical reaction, the Fenton reaction for initiating radical polymerizations, is demonstrated. The reaction between the Fenton reagents (i.e., Fe2+ and H2 O2 ) generates highly reactive hydroxyl radicals, which can act as radical initiators for the polymerization of vinyl monomers. Since the Fenton reaction is fast, easy to set up, cheap, and biocompatible, this unique chemistry is widely employed in various polymer synthesis studies via free radical polymerization or reversible addition-fragmentation chain transfer polymerization, and is utilized in a wide range of applications, such as the fabrication of biomaterials, hydrogels, and core-shell particles. Biologically activated Fenton-mediated radical polymerization, which can be performed in aerobic environments, are particularly useful for applications in biomedical systems. | |
dc.format | Print-Electronic | |
dc.language | eng | |
dc.publisher | WILEY-V C H VERLAG GMBH | |
dc.relation.ispartof | Macromolecular rapid communications | |
dc.relation.isbasedon | 10.1002/marc.201900220 | |
dc.rights | info:eu-repo/semantics/closedAccess | |
dc.subject | 03 Chemical Sciences, 09 Engineering | |
dc.subject.classification | Polymers | |
dc.subject.mesh | Animals | |
dc.subject.mesh | Hydrogen Peroxide | |
dc.subject.mesh | Iron | |
dc.subject.mesh | Free Radicals | |
dc.subject.mesh | Polymers | |
dc.subject.mesh | Biocompatible Materials | |
dc.subject.mesh | Hydrogels | |
dc.subject.mesh | Oxidation-Reduction | |
dc.subject.mesh | Polymerization | |
dc.subject.mesh | Animals | |
dc.subject.mesh | Biocompatible Materials | |
dc.subject.mesh | Free Radicals | |
dc.subject.mesh | Hydrogels | |
dc.subject.mesh | Hydrogen Peroxide | |
dc.subject.mesh | Iron | |
dc.subject.mesh | Oxidation-Reduction | |
dc.subject.mesh | Polymerization | |
dc.subject.mesh | Polymers | |
dc.title | Fenton-Chemistry-Mediated Radical Polymerization. | |
dc.type | Journal Article | |
utslib.citation.volume | 40 | |
utslib.location.activity | Germany | |
utslib.for | 03 Chemical Sciences | |
utslib.for | 09 Engineering | |
pubs.organisational-group | /University of Technology Sydney | |
pubs.organisational-group | /University of Technology Sydney/Faculty of Engineering and Information Technology | |
pubs.organisational-group | /University of Technology Sydney/Faculty of Engineering and Information Technology/School of Civil and Environmental Engineering | |
pubs.organisational-group | /University of Technology Sydney/Strength - CTWW - Centre for Technology in Water and Wastewater Treatment | |
utslib.copyright.status | closed_access | * |
dc.date.updated | 2021-03-30T23:12:01Z | |
pubs.issue | 18 | |
pubs.publication-status | Published | |
pubs.volume | 40 | |
utslib.citation.issue | 18 |
Abstract:
In this review, the power of a classical chemical reaction, the Fenton reaction for initiating radical polymerizations, is demonstrated. The reaction between the Fenton reagents (i.e., Fe2+ and H2 O2 ) generates highly reactive hydroxyl radicals, which can act as radical initiators for the polymerization of vinyl monomers. Since the Fenton reaction is fast, easy to set up, cheap, and biocompatible, this unique chemistry is widely employed in various polymer synthesis studies via free radical polymerization or reversible addition-fragmentation chain transfer polymerization, and is utilized in a wide range of applications, such as the fabrication of biomaterials, hydrogels, and core-shell particles. Biologically activated Fenton-mediated radical polymerization, which can be performed in aerobic environments, are particularly useful for applications in biomedical systems.
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