Three dimensional cellular architecture of sulfur doped graphene: self-standing electrode for flexible supercapacitors, lithium ion and sodium ion batteries

Islam, MM; Subramaniyam, CM; Akhter, T; Faisal, SN; Minett, AI; Liu, HK; Konstantinov, K; Dou, SX

Three dimensional cellular architecture of sulfur doped graphene: self-standing electrode for flexible supercapacitors, lithium ion and sodium ion batteries

Islam, MM Subramaniyam, CM Akhter, T Faisal, SN Minett, AI Liu, HK Konstantinov, K Dou, SX

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Publisher:: Royal Society of Chemistry
Publication Type:: Journal Article
Citation:: Journal of Materials Chemistry A, 2017, 5, (11), pp. 5290-5302
Issue Date:: 2017-01-01

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Field	Value	Language
dc.contributor.author	Islam, MM
dc.contributor.author	Subramaniyam, CM
dc.contributor.author	Akhter, T
dc.contributor.author	Faisal, SN
dc.contributor.author	Minett, AI
dc.contributor.author	Liu, HK
dc.contributor.author	Konstantinov, K
dc.contributor.author	Dou, SX
dc.date.accessioned	2022-07-15T01:59:56Z
dc.date.available	2022-07-15T01:59:56Z
dc.date.issued	2017-01-01
dc.identifier.citation	Journal of Materials Chemistry A, 2017, 5, (11), pp. 5290-5302
dc.identifier.issn	2050-7488
dc.identifier.issn	2050-7496
dc.identifier.uri	http://hdl.handle.net/10453/158938
dc.description.abstract	Tailoring the planar morphology of graphene and the generation of electron-dense active sites on its surface by heteroatom doping is one potential approach to enhance the charge storage performance of graphene based electrode materials. Herein, we have reported the preparation of a three-dimensional self-standing cellular architecture as sulfur-doped graphene foam (SGF) by using the simple self-assembly of poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) polymer chains on graphene oxide followed by thermal treatment. Successful homogeneous sulfur doping in a three-dimensional (3D) framework of graphene allowed the material to have a large surface area with bulk electroactive regions on the surface for better interfacial contact with electrolyte ions and hence resulted in unprecedented energy storage capability in a flexible aqueous symmetric supercapacitor (367 F g−1 at 1 A g−1), a lithium ion battery (1697 mA h g−1 at 100 mA g−1), and a sodium ion battery (472 mA h g−1 at 50 mA g−1) as a binder-free electrode material. The outstanding electrochemical performance of the material demonstrates the potential of this synthesis approach for various heteroatom-doped self-standing nano-carbon monoliths on a small as well as a large scale for high-performance energy device fabrication for the advancement of modern electronic devices.
dc.language	en
dc.publisher	Royal Society of Chemistry
dc.relation.ispartof	Journal of Materials Chemistry A
dc.relation.isbasedon	10.1039/c6ta10933k
dc.rights	info:eu-repo/semantics/closedAccess
dc.subject	0303 Macromolecular and Materials Chemistry, 0912 Materials Engineering, 0915 Interdisciplinary Engineering
dc.title	Three dimensional cellular architecture of sulfur doped graphene: self-standing electrode for flexible supercapacitors, lithium ion and sodium ion batteries
dc.type	Journal Article
utslib.citation.volume	5
utslib.for	0303 Macromolecular and Materials Chemistry
utslib.for	0912 Materials Engineering
utslib.for	0915 Interdisciplinary Engineering
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Engineering and Information Technology
pubs.organisational-group	/University of Technology Sydney/Faculty of Engineering and Information Technology/School of Electrical and Data Engineering
utslib.copyright.status	closed_access	*
pubs.consider-herdc	false
dc.date.updated	2022-07-15T01:59:54Z
pubs.issue	11
pubs.publication-status	Published
pubs.volume	5
utslib.citation.issue	11

Abstract:

Tailoring the planar morphology of graphene and the generation of electron-dense active sites on its surface by heteroatom doping is one potential approach to enhance the charge storage performance of graphene based electrode materials. Herein, we have reported the preparation of a three-dimensional self-standing cellular architecture as sulfur-doped graphene foam (SGF) by using the simple self-assembly of poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) polymer chains on graphene oxide followed by thermal treatment. Successful homogeneous sulfur doping in a three-dimensional (3D) framework of graphene allowed the material to have a large surface area with bulk electroactive regions on the surface for better interfacial contact with electrolyte ions and hence resulted in unprecedented energy storage capability in a flexible aqueous symmetric supercapacitor (367 F g−1 at 1 A g−1), a lithium ion battery (1697 mA h g−1 at 100 mA g−1), and a sodium ion battery (472 mA h g−1 at 50 mA g−1) as a binder-free electrode material. The outstanding electrochemical performance of the material demonstrates the potential of this synthesis approach for various heteroatom-doped self-standing nano-carbon monoliths on a small as well as a large scale for high-performance energy device fabrication for the advancement of modern electronic devices.

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http://hdl.handle.net/10453/158938