A High-Performance Rechargeable Mg(2+)/Li(+) Hybrid Battery Using One-Dimensional Mesoporous TiO2(B) Nanoflakes as the Cathode.

Su, S; NuLi, Y; Huang, Z; Miao, Q; Yang, J; Wang, J

A High-Performance Rechargeable Mg(2+)/Li(+) Hybrid Battery Using One-Dimensional Mesoporous TiO2(B) Nanoflakes as the Cathode.

Su, S NuLi, Y Huang, Z

Miao, Q Yang, J Wang, J

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Publisher:: AMER CHEMICAL SOC
Publication Type:: Journal Article
Citation:: ACS Appl Mater Interfaces, 2016, 8, (11), pp. 7111-7117
Issue Date:: 2016-03-23

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Field	Value	Language
dc.contributor.author	Su, S
dc.contributor.author	NuLi, Y
dc.contributor.author	Huang, Z https://orcid.org/0000-0003-1985-0884
dc.contributor.author	Miao, Q
dc.contributor.author	Yang, J
dc.contributor.author	Wang, J
dc.date.accessioned	2022-07-18T04:02:15Z
dc.date.available	2022-07-18T04:02:15Z
dc.date.issued	2016-03-23
dc.identifier.citation	ACS Appl Mater Interfaces, 2016, 8, (11), pp. 7111-7117
dc.identifier.issn	1944-8244
dc.identifier.issn	1944-8252
dc.identifier.uri	http://hdl.handle.net/10453/158984
dc.description.abstract	Mg(2+)/Li(+) hybrid batteries have recently been constructed combining a Mg anode, a Li(+)-intercalation electrode, and an electrolyte containing both Mg(2+) and Li(+). These batteries have been reported to outperform all the previously reported magnesium batteries in terms of specific capacity, cycling stability, and rate capability. Herein, we report the outstanding electrochemical performance of Mg(2+)/Li(+) hybrid batteries consisting of a one-dimensional mesoporous TiO2(B) cathode, a Mg anode, and an electrolyte consisting of 0.5 mol L(-1) Mg(BH4)2 + 1.5 mol L(-1) LiBH4 in tetraglyme. A highly synergetic interaction between Li(+) and Mg(2+) ions toward the pseudo-capacitive reaction is proposed. The hybrid batteries show superior rate performance with 130 mAh g(-1) at 1 C and 115 mAh g(-1) at 2 C, together with excellent cyclability up to 6000 cycles.
dc.format	Print-Electronic
dc.language	eng
dc.publisher	AMER CHEMICAL SOC
dc.relation.ispartof	ACS Appl Mater Interfaces
dc.relation.isbasedon	10.1021/acsami.6b00106
dc.rights	info:eu-repo/semantics/closedAccess
dc.subject	03 Chemical Sciences, 09 Engineering
dc.subject.classification	Nanoscience & Nanotechnology
dc.title	A High-Performance Rechargeable Mg(2+)/Li(+) Hybrid Battery Using One-Dimensional Mesoporous TiO2(B) Nanoflakes as the Cathode.
dc.type	Journal Article
utslib.citation.volume	8
utslib.location.activity	United States
utslib.for	03 Chemical Sciences
utslib.for	09 Engineering
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Engineering and Information Technology
pubs.organisational-group	/University of Technology Sydney/Faculty of Engineering and Information Technology/School of Civil and Environmental Engineering
pubs.organisational-group	/University of Technology Sydney/Strength - CTWW - Centre for Technology in Water and Wastewater Treatment
utslib.copyright.status	closed_access	*
dc.date.updated	2022-07-18T04:02:14Z
pubs.issue	11
pubs.publication-status	Published
pubs.volume	8
utslib.citation.issue	11

Abstract:

Mg(2+)/Li(+) hybrid batteries have recently been constructed combining a Mg anode, a Li(+)-intercalation electrode, and an electrolyte containing both Mg(2+) and Li(+). These batteries have been reported to outperform all the previously reported magnesium batteries in terms of specific capacity, cycling stability, and rate capability. Herein, we report the outstanding electrochemical performance of Mg(2+)/Li(+) hybrid batteries consisting of a one-dimensional mesoporous TiO2(B) cathode, a Mg anode, and an electrolyte consisting of 0.5 mol L(-1) Mg(BH4)2 + 1.5 mol L(-1) LiBH4 in tetraglyme. A highly synergetic interaction between Li(+) and Mg(2+) ions toward the pseudo-capacitive reaction is proposed. The hybrid batteries show superior rate performance with 130 mAh g(-1) at 1 C and 115 mAh g(-1) at 2 C, together with excellent cyclability up to 6000 cycles.

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http://hdl.handle.net/10453/158984