Sono-RAFT Polymerization in Aqueous Medium.

Publisher:
WILEY-V C H VERLAG GMBH
Publication Type:
Journal Article
Citation:
Angewandte Chemie - International Edition, 2017, 56, (40), pp. 12302-12306
Issue Date:
2017-09-25
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The ultrasonic irradiation of aqueous solution is demonstrated to be a suitable source of initiating radicals for a controlled radical polymerization when conducted in the presence of a thiocarbonylthio-containing reversible addition-fragmentation chain transfer (RAFT) agent. This allows for a highly "green" method of externally regulated/controlled polymerization with a potentially broad scope for polymerizable monomers and/or polymer structures.
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