Continuous assembly of a polymer on a metal-organic framework (CAP on MOF): A 30 nm thick polymeric gas separation membrane

Xie, K; Fu, Q; Xu, C; Lu, H; Zhao, Q; Curtain, R; Gu, D; Webley, PA; Qiao, GG

Continuous assembly of a polymer on a metal-organic framework (CAP on MOF): A 30 nm thick polymeric gas separation membrane

Xie, K Fu, Q

Xu, C Lu, H Zhao, Q Curtain, R Gu, D Webley, PA Qiao, GG

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Publisher:: ROYAL SOC CHEMISTRY
Publication Type:: Journal Article
Citation:: Energy and Environmental Science, 2018, 11, (3), pp. 544-550
Issue Date:: 2018-03-01

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Field	Value	Language
dc.contributor.author	Xie, K
dc.contributor.author	Fu, Q https://orcid.org/0000-0002-4012-330X
dc.contributor.author	Xu, C
dc.contributor.author	Lu, H
dc.contributor.author	Zhao, Q
dc.contributor.author	Curtain, R
dc.contributor.author	Gu, D
dc.contributor.author	Webley, PA
dc.contributor.author	Qiao, GG
dc.date.accessioned	2022-09-03T07:21:12Z
dc.date.available	2022-09-03T07:21:12Z
dc.date.issued	2018-03-01
dc.identifier.citation	Energy and Environmental Science, 2018, 11, (3), pp. 544-550
dc.identifier.issn	1754-5692
dc.identifier.issn	1754-5706
dc.identifier.uri	http://hdl.handle.net/10453/161262
dc.description.abstract	We have developed a bottom-up approach to fabricate an ultra-thin (∼30 nm), continuous and defect-free polymeric membrane on a rough micro-scale MOF layer. This polymer-on-MOF architecture exhibits a promising CO2/N2 separation performance with a CO2 permeance of >3000 GPU and a CO2/N2 selectivity of 34. To the best of our knowledge, this membrane has the best CO2/N2 separation performance compared to any other membrane reported in the open literature.
dc.language	English
dc.publisher	ROYAL SOC CHEMISTRY
dc.relation.ispartof	Energy and Environmental Science
dc.relation.isbasedon	10.1039/c7ee02820b
dc.rights	info:eu-repo/semantics/closedAccess
dc.subject.classification	Energy
dc.title	Continuous assembly of a polymer on a metal-organic framework (CAP on MOF): A 30 nm thick polymeric gas separation membrane
dc.type	Journal Article
utslib.citation.volume	11
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Engineering and Information Technology
pubs.organisational-group	/University of Technology Sydney/Faculty of Engineering and Information Technology/School of Civil and Environmental Engineering
pubs.organisational-group	/University of Technology Sydney/Strength - CTWW - Centre for Technology in Water and Wastewater Treatment
utslib.copyright.status	closed_access	*
dc.date.updated	2022-09-03T07:21:08Z
pubs.issue	3
pubs.publication-status	Published
pubs.volume	11
utslib.citation.issue	3

Abstract:

We have developed a bottom-up approach to fabricate an ultra-thin (∼30 nm), continuous and defect-free polymeric membrane on a rough micro-scale MOF layer. This polymer-on-MOF architecture exhibits a promising CO2/N2 separation performance with a CO2 permeance of >3000 GPU and a CO2/N2 selectivity of 34. To the best of our knowledge, this membrane has the best CO2/N2 separation performance compared to any other membrane reported in the open literature.

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http://hdl.handle.net/10453/161262