Blood-Catalyzed RAFT Polymerization.

Reyhani, A; Nothling, MD; Ranji-Burachaloo, H; McKenzie, TG; Fu, Q; Tan, S; Bryant, G; Qiao, GG

Blood-Catalyzed RAFT Polymerization.

Reyhani, A Nothling, MD Ranji-Burachaloo, H McKenzie, TG Fu, Q

Tan, S Bryant, G Qiao, GG

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Publisher:: WILEY-V C H VERLAG GMBH
Publication Type:: Journal Article
Citation:: Angew Chem Int Ed Engl, 2018, 57, (32), pp. 10288-10292
Issue Date:: 2018-08-06

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Field	Value	Language
dc.contributor.author	Reyhani, A
dc.contributor.author	Nothling, MD
dc.contributor.author	Ranji-Burachaloo, H
dc.contributor.author	McKenzie, TG
dc.contributor.author	Fu, Q https://orcid.org/0000-0002-4012-330X
dc.contributor.author	Tan, S
dc.contributor.author	Bryant, G
dc.contributor.author	Qiao, GG
dc.date.accessioned	2022-09-05T06:40:53Z
dc.date.available	2022-09-05T06:40:53Z
dc.date.issued	2018-08-06
dc.identifier.citation	Angew Chem Int Ed Engl, 2018, 57, (32), pp. 10288-10292
dc.identifier.issn	1433-7851
dc.identifier.issn	1521-3773
dc.identifier.uri	http://hdl.handle.net/10453/161368
dc.description.abstract	The use of hemoglobin (Hb) contained within red blood cells to drive a controlled radical polymerization via a reversible addition-fragmentation chain transfer (RAFT) process is reported for the first time. No pre-treatment of the Hb or cells was required prior to their use as polymerization catalysts, indicating the potential for synthetic engineering in complex biological microenvironments without the need for ex vivo techniques. Owing to the naturally occurring prevalence of the reagents employed in the catalytic system (Hb and hydrogen peroxide), this approach may facilitate the development of new strategies for in vivo cell engineering with synthetic macromolecules.
dc.format	Print-Electronic
dc.language	eng
dc.publisher	WILEY-V C H VERLAG GMBH
dc.relation.ispartof	Angew Chem Int Ed Engl
dc.relation.isbasedon	10.1002/anie.201802544
dc.rights	info:eu-repo/semantics/closedAccess
dc.subject	03 Chemical Sciences
dc.subject.classification	Organic Chemistry
dc.title	Blood-Catalyzed RAFT Polymerization.
dc.type	Journal Article
utslib.citation.volume	57
utslib.location.activity	Germany
utslib.for	03 Chemical Sciences
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Engineering and Information Technology
pubs.organisational-group	/University of Technology Sydney/Faculty of Engineering and Information Technology/School of Civil and Environmental Engineering
pubs.organisational-group	/University of Technology Sydney/Strength - CTWW - Centre for Technology in Water and Wastewater Treatment
utslib.copyright.status	closed_access	*
dc.date.updated	2022-09-05T06:40:51Z
pubs.issue	32
pubs.publication-status	Published
pubs.volume	57
utslib.citation.issue	32

Abstract:

The use of hemoglobin (Hb) contained within red blood cells to drive a controlled radical polymerization via a reversible addition-fragmentation chain transfer (RAFT) process is reported for the first time. No pre-treatment of the Hb or cells was required prior to their use as polymerization catalysts, indicating the potential for synthetic engineering in complex biological microenvironments without the need for ex vivo techniques. Owing to the naturally occurring prevalence of the reagents employed in the catalytic system (Hb and hydrogen peroxide), this approach may facilitate the development of new strategies for in vivo cell engineering with synthetic macromolecules.

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http://hdl.handle.net/10453/161368