Recovery of phosphorus from wastewater containing humic substances through vivianite crystallization: Interaction and mechanism analysis.

Wang, S-N; Cao, J-S; Zhang, J-L; Luo, J-Y; Ni, B-J; Fang, F

Recovery of phosphorus from wastewater containing humic substances through vivianite crystallization: Interaction and mechanism analysis.

Wang, S-N Cao, J-S Zhang, J-L Luo, J-Y Ni, B-J Fang, F

Permalink

Publisher:: Elsevier
Publication Type:: Journal Article
Citation:: J Environ Manage, 2023, 331, pp. 117324
Issue Date:: 2023-04-01

Closed Access

	Filename	Description	Size
	Recovery of phosphorus from wastewater.pdf		4.46 MB	Adobe PDF	View/Open

Copyright Clearance Process

Recently Added
In Progress
Closed Access

This item is closed access and not available.

Full metadata record

Field	Value	Language
dc.contributor.author	Wang, S-N
dc.contributor.author	Cao, J-S
dc.contributor.author	Zhang, J-L
dc.contributor.author	Luo, J-Y
dc.contributor.author	Ni, B-J
dc.contributor.author	Fang, F
dc.date.accessioned	2023-03-22T02:31:00Z
dc.date.available	2023-01-16
dc.date.available	2023-03-22T02:31:00Z
dc.date.issued	2023-04-01
dc.identifier.citation	J Environ Manage, 2023, 331, pp. 117324
dc.identifier.issn	0301-4797
dc.identifier.issn	1095-8630
dc.identifier.uri	http://hdl.handle.net/10453/168041
dc.description.abstract	Vivianite crystallization has been regarded as a suitable option for recovering phosphorus (P) from P-containing wastewater. However, the presence of humic substances (HS) would inevitably affect the formation of vivianite crystals. Therefore, the influences of HS on vivianite crystallization and the changes in the harvested vivianite crystals were investigated in this study. The results suggested the inhibition effect of 70 mg/L HS on vivianite crystallization reached 12.24%, while it could be attenuated by increasing the pH and Fe/P ratio of the solution. Meanwhile, the addition of HS altered the size, purity, and morphology of recovered vivianite crystals due to the blockage of the growth sites on the crystal surface. Additionally, the formation of phosphate ester group, hydrogen bonding, and COOH-Fe2+ complexes are the potential mechanisms of HS interaction with vivianite crystals. The results obtained herein will help to elucidate the underlying mechanism of HS on vivianite crystallization from P-containing wastewater.
dc.format	Print-Electronic
dc.language	eng
dc.publisher	Elsevier
dc.relation.ispartof	J Environ Manage
dc.relation.isbasedon	10.1016/j.jenvman.2023.117324
dc.rights	info:eu-repo/semantics/closedAccess
dc.subject.classification	Environmental Sciences
dc.subject.mesh	Phosphorus
dc.subject.mesh	Wastewater
dc.subject.mesh	Humic Substances
dc.subject.mesh	Crystallization
dc.subject.mesh	Waste Disposal, Fluid
dc.subject.mesh	Phosphates
dc.subject.mesh	Phosphates
dc.subject.mesh	Phosphorus
dc.subject.mesh	Humic Substances
dc.subject.mesh	Crystallization
dc.subject.mesh	Waste Disposal, Fluid
dc.subject.mesh	Wastewater
dc.title	Recovery of phosphorus from wastewater containing humic substances through vivianite crystallization: Interaction and mechanism analysis.
dc.type	Journal Article
utslib.citation.volume	331
utslib.location.activity	England
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Engineering and Information Technology
pubs.organisational-group	/University of Technology Sydney/Faculty of Engineering and Information Technology/School of Civil and Environmental Engineering
pubs.organisational-group	/University of Technology Sydney/Strength - CTWW - Centre for Technology in Water and Wastewater Treatment
utslib.copyright.status	closed_access	*
dc.date.updated	2023-03-22T02:30:55Z
pubs.publication-status	Published
pubs.volume	331

Abstract:

Vivianite crystallization has been regarded as a suitable option for recovering phosphorus (P) from P-containing wastewater. However, the presence of humic substances (HS) would inevitably affect the formation of vivianite crystals. Therefore, the influences of HS on vivianite crystallization and the changes in the harvested vivianite crystals were investigated in this study. The results suggested the inhibition effect of 70 mg/L HS on vivianite crystallization reached 12.24%, while it could be attenuated by increasing the pH and Fe/P ratio of the solution. Meanwhile, the addition of HS altered the size, purity, and morphology of recovered vivianite crystals due to the blockage of the growth sites on the crystal surface. Additionally, the formation of phosphate ester group, hydrogen bonding, and COOH-Fe2+ complexes are the potential mechanisms of HS interaction with vivianite crystals. The results obtained herein will help to elucidate the underlying mechanism of HS on vivianite crystallization from P-containing wastewater.

Please use this identifier to cite or link to this item:

http://hdl.handle.net/10453/168041