Nanostructure Engineering Strategies of Cathode Materials for Room-Temperature Na-S Batteries.

Wang, Y; Huang, XL; Liu, H; Qiu, W; Feng, C; Li, C; Zhang, S; Liu, HK; Dou, SX; Wang, ZM

Nanostructure Engineering Strategies of Cathode Materials for Room-Temperature Na-S Batteries.

Wang, Y Huang, XL Liu, H Qiu, W Feng, C Li, C Zhang, S Liu, HK Dou, SX Wang, ZM

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Publisher:: AMER CHEMICAL SOC
Publication Type:: Journal Article
Citation:: ACS Nano, 2022, 16, (4), pp. 5103-5130
Issue Date:: 2022-04-26

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Field	Value	Language
dc.contributor.author	Wang, Y
dc.contributor.author	Huang, XL
dc.contributor.author	Liu, H
dc.contributor.author	Qiu, W
dc.contributor.author	Feng, C
dc.contributor.author	Li, C
dc.contributor.author	Zhang, S
dc.contributor.author	Liu, HK
dc.contributor.author	Dou, SX
dc.contributor.author	Wang, ZM
dc.date.accessioned	2023-04-18T04:12:38Z
dc.date.available	2023-04-18T04:12:38Z
dc.date.issued	2022-04-26
dc.identifier.citation	ACS Nano, 2022, 16, (4), pp. 5103-5130
dc.identifier.issn	1936-0851
dc.identifier.issn	1936-086X
dc.identifier.uri	http://hdl.handle.net/10453/169937
dc.description.abstract	Room-temperature sodium-sulfur (RT Na-S) batteries are considered to be a competitive electrochemical energy storage system, due to their advantages in abundant natural reserves, inexpensive materials, and superb theoretical energy density. Nevertheless, RT Na-S batteries suffer from a series of critical challenges, especially on the S cathode side, including the insulating nature of S and its discharge products, volumetric fluctuation of S species during the (de)sodiation process, shuttle effect of soluble sodium polysulfides, and sluggish conversion kinetics. Recent studies have shown that nanostructural designs of S-based materials can greatly contribute to alleviating the aforementioned issues via their unique physicochemical properties and architectural features. In this review, we review frontier advancements in nanostructure engineering strategies of S-based cathode materials for RT Na-S batteries in the past decade. Our emphasis is focused on delicate and highly efficient design strategies of material nanostructures as well as interactions of component-structure-property at a nanosize level. We also present our prospects toward further functional engineering and applications of nanostructured S-based materials in RT Na-S batteries and point out some potential developmental directions.
dc.format	Print-Electronic
dc.language	eng
dc.publisher	AMER CHEMICAL SOC
dc.relation.ispartof	ACS Nano
dc.relation.isbasedon	10.1021/acsnano.2c00265
dc.rights	info:eu-repo/semantics/closedAccess
dc.subject.classification	Nanoscience & Nanotechnology
dc.title	Nanostructure Engineering Strategies of Cathode Materials for Room-Temperature Na-S Batteries.
dc.type	Journal Article
utslib.citation.volume	16
utslib.location.activity	United States
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Engineering and Information Technology
pubs.organisational-group	/University of Technology Sydney/Faculty of Engineering and Information Technology/School of Civil and Environmental Engineering
utslib.copyright.status	closed_access	*
dc.date.updated	2023-04-18T04:12:37Z
pubs.issue	4
pubs.publication-status	Published
pubs.volume	16
utslib.citation.issue	4

Abstract:

Room-temperature sodium-sulfur (RT Na-S) batteries are considered to be a competitive electrochemical energy storage system, due to their advantages in abundant natural reserves, inexpensive materials, and superb theoretical energy density. Nevertheless, RT Na-S batteries suffer from a series of critical challenges, especially on the S cathode side, including the insulating nature of S and its discharge products, volumetric fluctuation of S species during the (de)sodiation process, shuttle effect of soluble sodium polysulfides, and sluggish conversion kinetics. Recent studies have shown that nanostructural designs of S-based materials can greatly contribute to alleviating the aforementioned issues via their unique physicochemical properties and architectural features. In this review, we review frontier advancements in nanostructure engineering strategies of S-based cathode materials for RT Na-S batteries in the past decade. Our emphasis is focused on delicate and highly efficient design strategies of material nanostructures as well as interactions of component-structure-property at a nanosize level. We also present our prospects toward further functional engineering and applications of nanostructured S-based materials in RT Na-S batteries and point out some potential developmental directions.

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http://hdl.handle.net/10453/169937