Nanospace Engineering of Metal-Organic Frameworks for Heterogeneous Catalysis
- Publisher:
- Wiley
- Publication Type:
- Journal Article
- Citation:
- ChemNanoMat, 2022, 8, (1)
- Issue Date:
- 2022-01-01
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| Filename | Description | Size | |||
|---|---|---|---|---|---|
| ChemNanoMat - 2021 - Wang - Nanospace Engineering of Metal‐Organic Frameworks for Heterogeneous Catalysis.pdf | Published version | 4.86 MB |
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The structural advantages of metal organic frameworks MOFs can facilitate wide applications in the field of catalysis including oxidation hydrogenation acetalization transesterification catalytic cracking and so on The efficiency of catalysis is closely related to the synergy between active center auxiliary center and microenvironment Researchers can customize MOFs according to the needs of catalytic reactions and many strategies were established for boosting catalytic performance In this review we aim to summarize and illustrate recent progress in the nanospace engineering of MOFs Generally MOFs were engineered mainly from the following aspects 1 Regulation of pore size including micropores mesopores and macropores 2 Engineering of encapsulated active species such as metal nanoparticles quantum dots polyoxometalates enzymes etc 3 Engineering of MOFs morphology from zero dimension to three dimension 4 Controllable integration of MOFs with multi strategies 5 Construction of multivariate MOFs via introducing multiple or mixed organic functional groups into the existing framework Besides for further low cost and practical applications challenges for MOFs as green and sustainable catalysts are also discussed 2021 Wiley VCH GmbH
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