Effect of Carbonation on the Microstructure and Phase Development of High-Slag Binders

Publisher:
Springer
Publication Type:
Chapter
Citation:
Nanotechnology in Construction for Circular Economy, 2023, 356 LNCE, pp. 213-221
Issue Date:
2023-01-01
Full metadata record
The drive for sustainable concrete production favors the use of high replacement levels of supplementary cementitious materials (SCMs) in the concrete mix. The use of SCMs such as fly ash and slag, however, although they improve the sustainability of concrete production as well as most concrete durability properties, increases the carbonation rate. Carbonation decreases the pH of the concrete pore solution, making the steel reinforcement susceptible to corrosion. The effect of carbonation is, however, not confined to the change in pH of the pore solution. We investigated changes in the microstructure and phases of high-slag binders due to carbonation. The carbonation resistance of mortars with 50 and 70% slag replacement were investigated at exposure conditions of 2%CO2, 50%RH, 23 °C. The carbonated and non-carbonated parts of the mortars were subjected to various characterization techniques to investigate the effect of carbonation on microstructure and phase development. Results confirmed the absence of portlandite in all the carbonated regions (“colorless” by phenolphthalein test, which indicated that the change in color of the phenolphthalein solution was due to the absence of portlandite to buffer the pH). Significant reduction in the amount of C-S-H, as well as increase in the amount of calcium carbonate, were been observed in the carbonated regions. Aragonite, a polymorph of CaCO3, was very prominent in all the carbonated mortars.
Please use this identifier to cite or link to this item: