Ion transport and conduction in metal-organic framework glasses

Chai, M; Chen, R; Xu, K; Chen, Y; Ma, S; Lin, R; Chen, V; Hou, J

Ion transport and conduction in metal-organic framework glasses

Chai, M Chen, R Xu, K Chen, Y Ma, S Lin, R Chen, V

Hou, J

Permalink

Publisher:: Royal Society of Chemistry (RSC)
Publication Type:: Journal Article
Citation:: Journal of Materials Chemistry A, 2023, 11, (38), pp. 20302-20314
Issue Date:: 2023-08-17

Closed Access

	Filename	Description	Size
	d3ta03192f.pdf	Published version	1.14 MB	Adobe PDF	View/Open

Copyright Clearance Process

Recently Added
In Progress
Closed Access

This item is closed access and not available.

Full metadata record

Field	Value	Language
dc.contributor.author	Chai, M
dc.contributor.author	Chen, R
dc.contributor.author	Xu, K
dc.contributor.author	Chen, Y
dc.contributor.author	Ma, S
dc.contributor.author	Lin, R
dc.contributor.author	Chen, V https://orcid.org/0000-0002-6604-6197
dc.contributor.author	Hou, J
dc.date.accessioned	2024-05-10T19:32:20Z
dc.date.available	2024-05-10T19:32:20Z
dc.date.issued	2023-08-17
dc.identifier.citation	Journal of Materials Chemistry A, 2023, 11, (38), pp. 20302-20314
dc.identifier.issn	2050-7488
dc.identifier.issn	2050-7496
dc.identifier.uri	http://hdl.handle.net/10453/178830
dc.description.abstract	Metal-organic frameworks (MOFs) are a group of highly tunable porous materials composed of metal nodes and organic linkers. Although MOF research has predominantly focused on crystalline frameworks, amorphous MOFs with disordered structures have seen a surge in interest over the past few years. In particular, an emerging subgroup of amorphous MOFs exhibiting a glass transition temperature, known as MOF glass, offers several benefits as an ion conductor including the absence of grain boundaries, isotropic properties and high moldability. This perspective aims to explore the recent developments in MOF glass materials for ion transport and conduction. The mechanism and underlying factors that govern ion transport properties will be elucidated to guide the design of these materials with enhanced ion conductivity and selectivity. We also highlight their latest applications for electrochemical and energy related systems. Finally, we offer prospective strategies for tuning the ion transport characteristics in MOF glass to direct its implementation in current and future applications.
dc.language	en
dc.publisher	Royal Society of Chemistry (RSC)
dc.relation	http://purl.org/au-research/grants/arc/DP180103874
dc.relation.ispartof	Journal of Materials Chemistry A
dc.relation.isbasedon	10.1039/d3ta03192f
dc.rights	info:eu-repo/semantics/closedAccess
dc.subject	0303 Macromolecular and Materials Chemistry, 0912 Materials Engineering, 0915 Interdisciplinary Engineering
dc.subject.classification	3403 Macromolecular and materials chemistry
dc.subject.classification	4004 Chemical engineering
dc.subject.classification	4016 Materials engineering
dc.title	Ion transport and conduction in metal-organic framework glasses
dc.type	Journal Article
utslib.citation.volume	11
utslib.for	0303 Macromolecular and Materials Chemistry
utslib.for	0912 Materials Engineering
utslib.for	0915 Interdisciplinary Engineering
pubs.organisational-group	University of Technology Sydney
pubs.organisational-group	University of Technology Sydney/Provost
utslib.copyright.status	closed_access	*
dc.date.updated	2024-05-10T19:32:19Z
pubs.issue	38
pubs.publication-status	Published
pubs.volume	11
utslib.citation.issue	38

Abstract:

Metal-organic frameworks (MOFs) are a group of highly tunable porous materials composed of metal nodes and organic linkers. Although MOF research has predominantly focused on crystalline frameworks, amorphous MOFs with disordered structures have seen a surge in interest over the past few years. In particular, an emerging subgroup of amorphous MOFs exhibiting a glass transition temperature, known as MOF glass, offers several benefits as an ion conductor including the absence of grain boundaries, isotropic properties and high moldability. This perspective aims to explore the recent developments in MOF glass materials for ion transport and conduction. The mechanism and underlying factors that govern ion transport properties will be elucidated to guide the design of these materials with enhanced ion conductivity and selectivity. We also highlight their latest applications for electrochemical and energy related systems. Finally, we offer prospective strategies for tuning the ion transport characteristics in MOF glass to direct its implementation in current and future applications.

Please use this identifier to cite or link to this item:

http://hdl.handle.net/10453/178830