Metal-organic framework glass composites.

Lin, R; Chai, M; Zhou, Y; Chen, V; Bennett, TD; Hou, J

Metal-organic framework glass composites.

Lin, R Chai, M Zhou, Y Chen, V

Bennett, TD Hou, J

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Publisher:: Royal Society of Chemistry (RSC)
Publication Type:: Journal Article
Citation:: Chem Soc Rev, 2023, 52, (13), pp. 4149-4172
Issue Date:: 2023-07-03

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Field	Value	Language
dc.contributor.author	Lin, R
dc.contributor.author	Chai, M
dc.contributor.author	Zhou, Y
dc.contributor.author	Chen, V https://orcid.org/0000-0002-6604-6197
dc.contributor.author	Bennett, TD
dc.contributor.author	Hou, J
dc.date.accessioned	2024-05-16T19:59:47Z
dc.date.available	2024-05-16T19:59:47Z
dc.date.issued	2023-07-03
dc.identifier.citation	Chem Soc Rev, 2023, 52, (13), pp. 4149-4172
dc.identifier.issn	0306-0012
dc.identifier.issn	1460-4744
dc.identifier.uri	http://hdl.handle.net/10453/178994
dc.description.abstract	The melting phenomenon in metal-organic frameworks (MOFs) has been recognised as one of the fourth generation MOF paradigm behaviours. Molten MOFs have high processibility for producing mechanically robust glassy MOF macrostructures, and they also offer highly tunable interfacial characteristics when combined with other types of functional materials, such as crystalline MOFs, inorganic glass and metal halide perovskites. As a result, MOF glass composites have emerged as a family of functional materials with dynamic properties and hierarchical structural control. These nanocomposites allow for sophisticated materials science studies as well as the fabrication of next-generation separation, catalysis, optical, and biomedical devices. Here, we review the approaches for designing, fabricating, and characterising MOF glass composites. We determine the key application opportunities enabled by these composites and explore the remaining hurdles, such as improving thermal and chemical compatibility, regulating interfacial properties, and scalability.
dc.format	Electronic
dc.language	eng
dc.publisher	Royal Society of Chemistry (RSC)
dc.relation	http://purl.org/au-research/grants/arc/DP180103874
dc.relation.ispartof	Chem Soc Rev
dc.relation.isbasedon	10.1039/d2cs00315e
dc.rights	info:eu-repo/semantics/closedAccess
dc.subject	03 Chemical Sciences
dc.subject.classification	General Chemistry
dc.subject.classification	34 Chemical sciences
dc.subject.classification	40 Engineering
dc.title	Metal-organic framework glass composites.
dc.type	Journal Article
utslib.citation.volume	52
utslib.location.activity	England
utslib.for	03 Chemical Sciences
pubs.organisational-group	University of Technology Sydney
pubs.organisational-group	University of Technology Sydney/Provost
utslib.copyright.status	closed_access	*
dc.date.updated	2024-05-16T19:59:43Z
pubs.issue	13
pubs.publication-status	Published online
pubs.volume	52
utslib.citation.issue	13

Abstract:

The melting phenomenon in metal-organic frameworks (MOFs) has been recognised as one of the fourth generation MOF paradigm behaviours. Molten MOFs have high processibility for producing mechanically robust glassy MOF macrostructures, and they also offer highly tunable interfacial characteristics when combined with other types of functional materials, such as crystalline MOFs, inorganic glass and metal halide perovskites. As a result, MOF glass composites have emerged as a family of functional materials with dynamic properties and hierarchical structural control. These nanocomposites allow for sophisticated materials science studies as well as the fabrication of next-generation separation, catalysis, optical, and biomedical devices. Here, we review the approaches for designing, fabricating, and characterising MOF glass composites. We determine the key application opportunities enabled by these composites and explore the remaining hurdles, such as improving thermal and chemical compatibility, regulating interfacial properties, and scalability.

Please use this identifier to cite or link to this item:

http://hdl.handle.net/10453/178994