Innovations in metal-organic frameworks (MOFs): Pioneering adsorption approaches for persistent organic pollutant (POP) removal.

Marghade, D; Shelare, S; Prakash, C; Soudagar, MEM; Yunus Khan, TM; Kalam, MA

Innovations in metal-organic frameworks (MOFs): Pioneering adsorption approaches for persistent organic pollutant (POP) removal.

Marghade, D Shelare, S Prakash, C Soudagar, MEM Yunus Khan, TM Kalam, MA

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Publisher:: ACADEMIC PRESS INC ELSEVIER SCIENCE
Publication Type:: Journal Article
Citation:: Environ Res, 2024, 258, pp. 119404
Issue Date:: 2024-10-01

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Field	Value	Language
dc.contributor.author	Marghade, D
dc.contributor.author	Shelare, S
dc.contributor.author	Prakash, C
dc.contributor.author	Soudagar, MEM
dc.contributor.author	Yunus Khan, TM
dc.contributor.author	Kalam, MA
dc.date.accessioned	2025-03-31T05:43:38Z
dc.date.available	2024-06-10
dc.date.available	2025-03-31T05:43:38Z
dc.date.issued	2024-10-01
dc.identifier.citation	Environ Res, 2024, 258, pp. 119404
dc.identifier.issn	0013-9351
dc.identifier.issn	1096-0953
dc.identifier.uri	http://hdl.handle.net/10453/186369
dc.description.abstract	Adsorption is a promising way to remove persistent organic pollutants (POPs), a major environmental issue. With their high porosity and vast surface areas, MOFs are suited for POP removal due to their excellent adsorption capabilities. This review addresses the intricate principles of MOF-mediated adsorption and helps to future attempts to mitigate organic water pollution. This review examines the complicated concepts of MOF-mediated adsorption, including MOF synthesis methodologies, adsorption mechanisms, and material tunability and adaptability. MOFs' ability to adsorb POPs via electrostatic forces, acid-base interactions, hydrogen bonds, and pi-pi interactions is elaborated. This review demonstrates its versatility in eliminating many types of contaminants. Functionalizing, adding metal nanoparticles, or changing MOFs after they are created can improve their performance and remove contaminants. This paper also discusses MOF-based pollutant removal issues and future prospects, including adsorption capacity, selectivity, scale-up for practical application, stability, and recovery. These obstacles can be overcome by rationally designing MOFs, developing composite materials, and improving material production and characterization. Overall, MOF technology research and innovation hold considerable promise for environmental pollution solutions and sustainable remediation. Desorption and regeneration in MOFs are also included in the review, along with methods for improving pollutant removal efficiency and sustainability. Case studies of effective MOF regeneration and scaling up for practical deployment are discussed, along with future ideas for addressing these hurdles.
dc.format	Print-Electronic
dc.language	eng
dc.publisher	ACADEMIC PRESS INC ELSEVIER SCIENCE
dc.relation.ispartof	Environ Res
dc.relation.isbasedon	10.1016/j.envres.2024.119404
dc.rights	info:eu-repo/semantics/closedAccess
dc.subject	03 Chemical Sciences, 05 Environmental Sciences, 06 Biological Sciences
dc.subject.classification	Toxicology
dc.subject.classification	31 Biological sciences
dc.subject.classification	34 Chemical sciences
dc.subject.classification	41 Environmental sciences
dc.subject.mesh	Adsorption
dc.subject.mesh	Metal-Organic Frameworks
dc.subject.mesh	Persistent Organic Pollutants
dc.subject.mesh	Water Pollutants, Chemical
dc.subject.mesh	Water Pollutants, Chemical
dc.subject.mesh	Adsorption
dc.subject.mesh	Metal-Organic Frameworks
dc.subject.mesh	Persistent Organic Pollutants
dc.subject.mesh	Adsorption
dc.subject.mesh	Metal-Organic Frameworks
dc.subject.mesh	Persistent Organic Pollutants
dc.subject.mesh	Water Pollutants, Chemical
dc.title	Innovations in metal-organic frameworks (MOFs): Pioneering adsorption approaches for persistent organic pollutant (POP) removal.
dc.type	Journal Article
utslib.citation.volume	258
utslib.location.activity	Netherlands
utslib.for	03 Chemical Sciences
utslib.for	05 Environmental Sciences
utslib.for	06 Biological Sciences
pubs.organisational-group	University of Technology Sydney
pubs.organisational-group	University of Technology Sydney/Faculty of Engineering and Information Technology
pubs.organisational-group	University of Technology Sydney/Faculty of Engineering and Information Technology/School of Civil and Environmental Engineering
utslib.copyright.status	closed_access	*
dc.date.updated	2025-03-31T05:43:36Z
pubs.publication-status	Published
pubs.volume	258

Abstract:

Adsorption is a promising way to remove persistent organic pollutants (POPs), a major environmental issue. With their high porosity and vast surface areas, MOFs are suited for POP removal due to their excellent adsorption capabilities. This review addresses the intricate principles of MOF-mediated adsorption and helps to future attempts to mitigate organic water pollution. This review examines the complicated concepts of MOF-mediated adsorption, including MOF synthesis methodologies, adsorption mechanisms, and material tunability and adaptability. MOFs' ability to adsorb POPs via electrostatic forces, acid-base interactions, hydrogen bonds, and pi-pi interactions is elaborated. This review demonstrates its versatility in eliminating many types of contaminants. Functionalizing, adding metal nanoparticles, or changing MOFs after they are created can improve their performance and remove contaminants. This paper also discusses MOF-based pollutant removal issues and future prospects, including adsorption capacity, selectivity, scale-up for practical application, stability, and recovery. These obstacles can be overcome by rationally designing MOFs, developing composite materials, and improving material production and characterization. Overall, MOF technology research and innovation hold considerable promise for environmental pollution solutions and sustainable remediation. Desorption and regeneration in MOFs are also included in the review, along with methods for improving pollutant removal efficiency and sustainability. Case studies of effective MOF regeneration and scaling up for practical deployment are discussed, along with future ideas for addressing these hurdles.

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http://hdl.handle.net/10453/186369