Intermarrying MOF Glass and Lead Halide Perovskites for Artificial Photosynthesis.

Huang, W; Chan, B; Yang, Y; Chen, P; Wang, J; Casey, L; Atzori, C; Schulli, T; Mathon, O; Hackbarth, HG; Bedford, NM; Appadoo, D; Li, X; Lin, T; Lin, R; Lee, J; Wang, Z; Chen, V; Cheetham, AK; Wang, L; Hou, J

Intermarrying MOF Glass and Lead Halide Perovskites for Artificial Photosynthesis.

Huang, W Chan, B Yang, Y Chen, P Wang, J Casey, L Atzori, C Schulli, T Mathon, O Hackbarth, HG Bedford, NM Appadoo, D Li, X Lin, T Lin, R Lee, J Wang, Z Chen, V

Cheetham, AK Wang, L Hou, J

Permalink

Publisher:: American Chemical Society (ACS)
Publication Type:: Journal Article
Citation:: J Am Chem Soc, 2025, 147, (4), pp. 3195-3205
Issue Date:: 2025-01-29

Closed Access

	Filename	Description	Size
	intermarrying-mof-glass-and-lead-halide-perovskites-for-artificial-photosynthesis.pdf	Published version	8.18 MB	Adobe PDF	View/Open

Copyright Clearance Process

Recently Added
In Progress
Closed Access

This item is closed access and not available.

Full metadata record

Field	Value	Language
dc.contributor.author	Huang, W
dc.contributor.author	Chan, B
dc.contributor.author	Yang, Y
dc.contributor.author	Chen, P
dc.contributor.author	Wang, J
dc.contributor.author	Casey, L
dc.contributor.author	Atzori, C
dc.contributor.author	Schulli, T
dc.contributor.author	Mathon, O
dc.contributor.author	Hackbarth, HG
dc.contributor.author	Bedford, NM
dc.contributor.author	Appadoo, D
dc.contributor.author	Li, X
dc.contributor.author	Lin, T
dc.contributor.author	Lin, R
dc.contributor.author	Lee, J
dc.contributor.author	Wang, Z
dc.contributor.author	Chen, V https://orcid.org/0000-0002-6604-6197
dc.contributor.author	Cheetham, AK
dc.contributor.author	Wang, L
dc.contributor.author	Hou, J
dc.date.accessioned	2026-03-09T06:01:32Z
dc.date.available	2026-03-09T06:01:32Z
dc.date.issued	2025-01-29
dc.identifier.citation	J Am Chem Soc, 2025, 147, (4), pp. 3195-3205
dc.identifier.issn	0002-7863
dc.identifier.issn	1520-5126
dc.identifier.uri	http://hdl.handle.net/10453/193803
dc.description.abstract	The development of efficient artificial photosynthesis systems is crucial for sustainable chemical production, as they mimic natural processes to convert solar energy into chemical products, thereby addressing both energy and environmental challenges. The main bottlenecks in current research include fabricating highly selective, stable, and scalable catalysts, as well as effectively harnessing the full spectrum of light, particularly the low-energy, long-wavelength portion. Herein, we report a novel composite photocatalyst system based on lead halide perovskites embedded in functionalized MOF glass. The construction of a well-defined interface between the light-harvesting perovskite and stable Rh single-atom-containing MOF glass mimics the functions of photosystem I (PS I). This facilitates efficient photoinduced electron generation under visible light and subsequent electron transfer for coenzyme (NADH) regeneration with high selectivity. The regenerated NADH can then be consumed by immobilized enzymes for CO2 reduction, realizing the artificial photosynthesis process for formic acid generation. This work also elucidates the interactions and optoelectronic responses between MOF glass and perovskites, offering insights into the design and fabrication of nanocomposite photocatalysts for other advanced chemical syntheses.
dc.format	Print-Electronic
dc.language	eng
dc.publisher	American Chemical Society (ACS)
dc.relation	http://purl.org/au-research/grants/arc/DP230101901
dc.relation.ispartof	J Am Chem Soc
dc.relation.isbasedon	10.1021/jacs.4c12619
dc.rights	info:eu-repo/semantics/closedAccess
dc.subject	03 Chemical Sciences
dc.subject.classification	General Chemistry
dc.subject.classification	34 Chemical sciences
dc.subject.classification	40 Engineering
dc.title	Intermarrying MOF Glass and Lead Halide Perovskites for Artificial Photosynthesis.
dc.type	Journal Article
utslib.citation.volume	147
utslib.location.activity	United States
utslib.for	03 Chemical Sciences
pubs.organisational-group	University of Technology Sydney
pubs.organisational-group	University of Technology Sydney/Provost
utslib.copyright.status	closed_access	*
dc.date.updated	2026-03-09T06:01:17Z
pubs.issue	4
pubs.publication-status	Published
pubs.volume	147
utslib.citation.issue	4

Abstract:

The development of efficient artificial photosynthesis systems is crucial for sustainable chemical production, as they mimic natural processes to convert solar energy into chemical products, thereby addressing both energy and environmental challenges. The main bottlenecks in current research include fabricating highly selective, stable, and scalable catalysts, as well as effectively harnessing the full spectrum of light, particularly the low-energy, long-wavelength portion. Herein, we report a novel composite photocatalyst system based on lead halide perovskites embedded in functionalized MOF glass. The construction of a well-defined interface between the light-harvesting perovskite and stable Rh single-atom-containing MOF glass mimics the functions of photosystem I (PS I). This facilitates efficient photoinduced electron generation under visible light and subsequent electron transfer for coenzyme (NADH) regeneration with high selectivity. The regenerated NADH can then be consumed by immobilized enzymes for CO2 reduction, realizing the artificial photosynthesis process for formic acid generation. This work also elucidates the interactions and optoelectronic responses between MOF glass and perovskites, offering insights into the design and fabrication of nanocomposite photocatalysts for other advanced chemical syntheses.

Please use this identifier to cite or link to this item:

http://hdl.handle.net/10453/193803