A continuous photocatalysis system in the degradation of herbicide

Publisher:
Korean Institute of Chemical Engineering
Publication Type:
Journal Article
Citation:
Korean Journal of Chemical Engineering, 2008, 25 (4), pp. 663 - 669
Issue Date:
2008-01
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The performance of both batch and continuous photo-catalytic reactors was studied to evaluate their capabilities in removing the sulfonyl urea herbicide of metsulfuron methyl (MM). It was found in a batch reactor that the addition of a small amount of powder activated carbon (PAC) significantly increased the rate of degradation of MM. The continuous photo-catalytic system resulted in 57% of MM removal. When a small dose of activated carbon was added in the photo-catalytic system, MM removal increased to 7886% MM removal for retention times between of 5.2521 min (corresponding to withdrawal rates of 1040 mLmin-1). In this study, the pseudo first order rate constants of a continuous photo-catalytic system revealed that shorter retention times were associated with lower rate constants. Solid phase micro extraction/gas chromatography (SPME/GC) results showed that high concentrations of MM were broken down to small volatile organic compounds (VOCs) by photo-catalytic oxidation. PAC adsorbed the photo-products and increased the degradation of MM.
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