Rubidium extraction using an organic polymer encapsulated potassium copper hexacyanoferrate sorbent

Naidu, G; Loganathan, P; Jeong, S; Johir, MAH; To, VHP; Kandasamy, J; Vigneswaran, S

Rubidium extraction using an organic polymer encapsulated potassium copper hexacyanoferrate sorbent

Naidu, G

Loganathan, P Jeong, S Johir, MAH

To, VHP Kandasamy, J Vigneswaran, S

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Publication Type:: Journal Article
Citation:: Chemical Engineering Journal, 2016, 306 pp. 31 - 42
Issue Date:: 2016-12-15

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Field	Value	Language
dc.contributor.author	Naidu, G https://orcid.org/0000-0002-6406-3444	en_US
dc.contributor.author	Loganathan, P	en_US
dc.contributor.author	Jeong, S	en_US
dc.contributor.author	Johir, MAH https://orcid.org/0000-0001-6222-6943	en_US
dc.contributor.author	To, VHP	en_US
dc.contributor.author	Kandasamy, J	en_US
dc.contributor.author	Vigneswaran, S https://orcid.org/0000-0002-8117-4322	en_US
dc.date.available	2020-05-25T19:06:16Z
dc.date.issued	2016-12-15	en_US
dc.identifier.citation	Chemical Engineering Journal, 2016, 306 pp. 31 - 42	en_US
dc.identifier.issn	1385-8947	en_US
dc.identifier.uri	http://hdl.handle.net/10453/98472
dc.description.abstract	© 2016 Elsevier B.V. Sea water reverse osmosis (SWRO) brine contains significant quantity of Rb. As an economically valuable metal, extracting Rb using a suitable and selective extraction method would be beneficial. An inorganic sorbent, copper based potassium hexacyanoferrate (KCuFC), exhibited high selectivity to extract Rb compared to potassium hexacyanoferrate consisting of other transition metal combinations such as Ni, Co and Fe. An organic polymer (polyacrylonitrile, PAN) encapsulated KCuFC (KCuFC-PAN) achieved a Langmuir maximum Rb sorption capacity of 1.23 mmol/g at pH 7.0 ± 0.5. KCuFC-PAN showed Rb selectivity over a wide concentration range of co-existing ions and salinity of SWRO brine. High salinity (0.5–2.5 M NaCl) resulted in 12–30% sorption capacity reduction. At a molar ratio of Li:Rb (21:1), Cs:Rb (0.001:1) and Ca:Rb (14,700:1) commonly found in SWRO brine, sorption reduction of only 18% occurred. Nevertheless, at a very high K:Rb molar ratio (7700:1), KCuFC-PAN sorption capacity of Rb reduced significantly by 65–70%. KCuFC-PAN was well suited for column operation. In a fixed-bed KCuFC-PAN column (influent concentration 0.06 mmol Rb/L, flow velocity 2 m/h), two sorption/desorption cycles were successfully achieved with a maximum Rb sorption capacity of 1.01 (closely similar to the batch study) and 0.85 mmol/g in the first and second cycles, respectively. Around 95% of Rb was desorbed from the column with 0.2 M KCl. Resorcinol formaldehyde (RF) resin showed promising results of separating Rb from K/Rb mixed solution in effluents from a fixed-bed column, and a subsequent sequential acid desorption, producing 68% purified Rb.	en_US
dc.relation	http://purl.org/au-research/grants/arc/DP150101377
dc.relation.ispartof	Chemical Engineering Journal	en_US
dc.relation.isbasedon	10.1016/j.cej.2016.07.038	en_US
dc.subject.classification	Chemical Engineering	en_US
dc.title	Rubidium extraction using an organic polymer encapsulated potassium copper hexacyanoferrate sorbent	en_US
dc.type	Journal Article
utslib.citation.volume	306	en_US
utslib.for	0904 Chemical Engineering	en_US
utslib.for	0905 Civil Engineering	en_US
utslib.for	0907 Environmental Engineering	en_US
pubs.embargo.period	Not known	en_US
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Engineering and Information Technology
pubs.organisational-group	/University of Technology Sydney/Faculty of Engineering and Information Technology/School of Civil and Environmental Engineering
pubs.organisational-group	/University of Technology Sydney/Strength - CTWW - Centre for Technology in Water and Wastewater Treatment
utslib.copyright.status	open_access
pubs.publication-status	Published	en_US
pubs.volume	306	en_US

Abstract:

© 2016 Elsevier B.V. Sea water reverse osmosis (SWRO) brine contains significant quantity of Rb. As an economically valuable metal, extracting Rb using a suitable and selective extraction method would be beneficial. An inorganic sorbent, copper based potassium hexacyanoferrate (KCuFC), exhibited high selectivity to extract Rb compared to potassium hexacyanoferrate consisting of other transition metal combinations such as Ni, Co and Fe. An organic polymer (polyacrylonitrile, PAN) encapsulated KCuFC (KCuFC-PAN) achieved a Langmuir maximum Rb sorption capacity of 1.23 mmol/g at pH 7.0 ± 0.5. KCuFC-PAN showed Rb selectivity over a wide concentration range of co-existing ions and salinity of SWRO brine. High salinity (0.5–2.5 M NaCl) resulted in 12–30% sorption capacity reduction. At a molar ratio of Li:Rb (21:1), Cs:Rb (0.001:1) and Ca:Rb (14,700:1) commonly found in SWRO brine, sorption reduction of only 18% occurred. Nevertheless, at a very high K:Rb molar ratio (7700:1), KCuFC-PAN sorption capacity of Rb reduced significantly by 65–70%. KCuFC-PAN was well suited for column operation. In a fixed-bed KCuFC-PAN column (influent concentration 0.06 mmol Rb/L, flow velocity 2 m/h), two sorption/desorption cycles were successfully achieved with a maximum Rb sorption capacity of 1.01 (closely similar to the batch study) and 0.85 mmol/g in the first and second cycles, respectively. Around 95% of Rb was desorbed from the column with 0.2 M KCl. Resorcinol formaldehyde (RF) resin showed promising results of separating Rb from K/Rb mixed solution in effluents from a fixed-bed column, and a subsequent sequential acid desorption, producing 68% purified Rb.

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http://hdl.handle.net/10453/98472