In situ formed internal water channels improving water swelling and mechanical properties of water swellable rubber composites
- Publisher:
- Wiley
- Publication Type:
- Journal Article
- Citation:
- Journal of Applied Polymer Science, 2017, 134, (9), pp. 1-6
- Issue Date:
- 2017-03-05
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In this study, electrospun nanofibers of poly (vinyl alcohol) (PVA) and styrene–butadiene–styrene triblock copolymer (SBS) were employed in conventional water-swellable rubber (WSR) to design WSR composites with improved water swelling and mechanical properties. With the introduction of PVA nanofibers, considerable improvement in elasticity, strength, and water-swelling behavior was observed. After immersion, PVA nanofibers dissolved within the composite to in situ form water channels to connect isolated super-absorbent polymers (SAPs). Those water channels led to an increase in water uptake by the WSR composite. Furthermore, the secondary water-swelling behaviors of the WSR composite showed a remarkable increase in swelling rate as well as in mechanical properties. The addition of SBS nanofibers had a marked impact on the mechanical properties of the WSR composite. Their roles became more pronounced after water immersion. The proposed enhancement mechanism is also discussed. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 44548.
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