Controlled Growth and Quantum Emitter Integration in Hexagonal Boron Nitride

Publication Type:
Thesis
Issue Date:
2025
Full metadata record
Quantum technologies offer transformative potential for computing, communication, and sensing, but practical implementation requires reliable single-photon sources. Defects in solid-state materials are among the most promising candidates for such sources. Two-dimensional materials, particularly hexagonal boron nitride, are highly favourable due to their ease of integration with photonic devices, controllable defect creation, high emission efficiency, and spin-active properties. While diamond and silicon carbide exhibit bright and stable emission, integrating them with nanoscale devices remains challenging. Hexagonal boron nitride, being atomically thin and free of dangling bonds, can host bright single-photon emitters and be incorporated into nanophotonic structures and heterostructures. In this thesis, scalable methods to create and control quantum emitters in hexagonal boron nitride are developed. Low-pressure chemical vapor deposition growth was optimized for uniform and crystalline films. Homoepitaxial growth was investigated to study the influence of lattice coherence on defect formation and emission quality. Structured defect engineering enabled the activation of bright, stable emitters. Comprehensive optical characterization was performed, and plasmonic coupling of boron vacancy spin defects was demonstrated to enhance light-matter interaction and advance integration with quantum photonic devices.
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