Design of an ultra-durable silicon-based battery anode material with exceptional high-temperature cycling stability

Park, H; Choi, S; Lee, SJ; Cho, YG; Hwang, G; Song, HK; Choi, NS; Park, S

Design of an ultra-durable silicon-based battery anode material with exceptional high-temperature cycling stability

Park, H Choi, S Lee, SJ Cho, YG Hwang, G Song, HK Choi, NS Park, S

Permalink

Publication Type:: Journal Article
Citation:: Nano Energy, 2016, 26 pp. 192 - 199
Issue Date:: 2016-08-01

Closed Access

	Filename	Description	Size
	1-s2.0-S2211285516301525-main.pdf	Published Version	2.52 MB	Adobe PDF	View/Open

Copyright Clearance Process

Recently Added
In Progress
Closed Access

This item is closed access and not available.

Full metadata record

Field	Value	Language
dc.contributor.author	Park, H	en_US
dc.contributor.author	Choi, S	en_US
dc.contributor.author	Lee, SJ	en_US
dc.contributor.author	Cho, YG	en_US
dc.contributor.author	Hwang, G	en_US
dc.contributor.author	Song, HK	en_US
dc.contributor.author	Choi, NS	en_US
dc.contributor.author	Park, S	en_US
dc.date.issued	2016-08-01	en_US
dc.identifier.citation	Nano Energy, 2016, 26 pp. 192 - 199	en_US
dc.identifier.issn	2211-2855	en_US
dc.identifier.uri	http://hdl.handle.net/10453/102511
dc.description.abstract	© 2016. Nanostructured silicon is a promising candidate material for practical use in energy storage devices. However, high temperature operation remains a significant challenge because of severe electrochemical side reactions. Here, we show the design of ultra-durable silicon made by introducing dual coating layers on the silicon surface, allowing stable operation at high temperature. The double layers, which consist of amorphous metal titanate and carbon, provide several advantages including: (i) suppression of volume expansion during Li+ insertion; (ii) creation of a stable solid-electrolyte-interface layer; and (iii) preservation of original Si morphology over 600 cycles at high temperature. The resulting silicon-based anode exhibits a reversible capacity of 990 mA h g-1 after 500 cycles at 25 °C and 1300 mA h g-1 after 600 cycles at 60 °C with a rate of 1 C.	en_US
dc.relation.ispartof	Nano Energy	en_US
dc.relation.isbasedon	10.1016/j.nanoen.2016.05.030	en_US
dc.title	Design of an ultra-durable silicon-based battery anode material with exceptional high-temperature cycling stability	en_US
dc.type	Journal Article
utslib.citation.volume	26	en_US
utslib.for	0303 Macromolecular and Materials Chemistry	en_US
utslib.for	0912 Materials Engineering	en_US
utslib.for	1007 Nanotechnology	en_US
pubs.embargo.period	Not known	en_US
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
pubs.organisational-group	/University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
pubs.organisational-group	/University of Technology Sydney/Strength - CCET - Centre for Clean Energy Technology
utslib.copyright.status	closed_access
pubs.publication-status	Published	en_US
pubs.volume	26	en_US

Abstract:

© 2016. Nanostructured silicon is a promising candidate material for practical use in energy storage devices. However, high temperature operation remains a significant challenge because of severe electrochemical side reactions. Here, we show the design of ultra-durable silicon made by introducing dual coating layers on the silicon surface, allowing stable operation at high temperature. The double layers, which consist of amorphous metal titanate and carbon, provide several advantages including: (i) suppression of volume expansion during Li+ insertion; (ii) creation of a stable solid-electrolyte-interface layer; and (iii) preservation of original Si morphology over 600 cycles at high temperature. The resulting silicon-based anode exhibits a reversible capacity of 990 mA h g-1 after 500 cycles at 25 °C and 1300 mA h g-1 after 600 cycles at 60 °C with a rate of 1 C.

Please use this identifier to cite or link to this item:

http://hdl.handle.net/10453/102511