Ultrafast modification of elements distribution and local luminescence properties in glass

Publication Type:
Journal Article
Citation:
Journal of Non-Crystalline Solids, 2012, 358 (9), pp. 1185 - 1189
Issue Date:
2012-05-01
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The success in construction of three-dimensional micro optical components or devices inside transparent materials is highly dependent on the ability to modify materials' local structure. Especially, the realization of space-selective manipulation of element distribution is highly desirable since most of optical parameters such as refractive index and luminescence are closely related to element distribution. Up to present, the only way to control selective element distribution is local melting of glass. Here, we reported, for the first time to our knowledge, the success in realization of space-selective manipulation of element distribution in glassy state region (i.e., un-melted region) inside glass with the irradiation of high repetition rate femtosecond laser. Confocal fluorescence spectra and micro-Raman spectra show that the luminescence distribution of Cu + ions and the glass network structure can be controlled with femtosecond laser irradiation, revealing the potential applications of this technique in the fabrication of functional waveguides and integrated optical devices. © 2012 Elsevier B.V. All rights reserved.
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