Phosphine-Borane complexes: In situ deprotection and application as ligands in the Rh- or Pd-Catalysed hydroformylation reaction

Williams, DBG; Kotze, PDR; Ferreira, AC; Holzapfel, CW

Phosphine-Borane complexes: In situ deprotection and application as ligands in the Rh- or Pd-Catalysed hydroformylation reaction

Williams, DBG

Kotze, PDR Ferreira, AC Holzapfel, CW

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Publication Type:: Journal Article
Citation:: Journal of the Iranian Chemical Society, 2011, 8 (1), pp. 240 - 246
Issue Date:: 2011-01-01

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Field	Value	Language
dc.contributor.author	Williams, DBG https://orcid.org/0000-0002-3703-6301	en_US
dc.contributor.author	Kotze, PDR	en_US
dc.contributor.author	Ferreira, AC	en_US
dc.contributor.author	Holzapfel, CW	en_US
dc.date.issued	2011-01-01	en_US
dc.identifier.citation	Journal of the Iranian Chemical Society, 2011, 8 (1), pp. 240 - 246	en_US
dc.identifier.issn	1735-207X	en_US
dc.identifier.uri	http://hdl.handle.net/10453/116078
dc.description.abstract	Triarylphosphine-borane complexes are directly useful in the Rh-catalysed hydroformylation reaction of 1-octene (or Pdcatalysed hydroformylation of 1-pentene). Mild reaction conditions provide similar yields and selectivities of the anticipated aldehyde products to reactions making use of the corresponding free phosphines as ligands. The mono- or bidentate P-B adducts undergo in situ CO-mediated deprotection the produce the free phosphine ligands. The results demonstrate that phosphine-borane complexes may be directly applied to carbonylation reactions without a prior deprotection step, with little to no change in the reaction outcome.	en_US
dc.relation.ispartof	Journal of the Iranian Chemical Society	en_US
dc.relation.isbasedon	10.1007/BF03246221	en_US
dc.subject.classification	General Chemistry	en_US
dc.title	Phosphine-Borane complexes: In situ deprotection and application as ligands in the Rh- or Pd-Catalysed hydroformylation reaction	en_US
dc.type	Journal Article
utslib.citation.volume	1	en_US
utslib.citation.volume	8	en_US
utslib.for	0303 Macromolecular and Materials Chemistry	en_US
utslib.for	0302 Inorganic Chemistry	en_US
utslib.for	03 Chemical Sciences	en_US
pubs.embargo.period	Not known	en_US
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
utslib.copyright.status	closed_access
pubs.issue	1	en_US
pubs.publication-status	Published	en_US
pubs.volume	8	en_US

Abstract:

Triarylphosphine-borane complexes are directly useful in the Rh-catalysed hydroformylation reaction of 1-octene (or Pdcatalysed hydroformylation of 1-pentene). Mild reaction conditions provide similar yields and selectivities of the anticipated aldehyde products to reactions making use of the corresponding free phosphines as ligands. The mono- or bidentate P-B adducts undergo in situ CO-mediated deprotection the produce the free phosphine ligands. The results demonstrate that phosphine-borane complexes may be directly applied to carbonylation reactions without a prior deprotection step, with little to no change in the reaction outcome.

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http://hdl.handle.net/10453/116078