Rac-[2-(Dicyclohexylphosphanyl)phenyl](phenyl)phosphinic diisopropylamide-borane hemihydrate

Evans, SJ; Renison, CA; Williams, DBG; Muller, A

Rac-[2-(Dicyclohexylphosphanyl)phenyl](phenyl)phosphinic diisopropylamide-borane hemihydrate

Evans, SJ Renison, CA Williams, DBG

Muller, A

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Publication Type:: Journal Article
Citation:: Acta Crystallographica Section E: Structure Reports Online, 2013, 69 (2)
Issue Date:: 2013-02-01

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Field	Value	Language
dc.contributor.author	Evans, SJ	en_US
dc.contributor.author	Renison, CA	en_US
dc.contributor.author	Williams, DBG https://orcid.org/0000-0002-3703-6301	en_US
dc.contributor.author	Muller, A	en_US
dc.date.available	2013-01-18	en_US
dc.date.issued	2013-02-01	en_US
dc.identifier.citation	Acta Crystallographica Section E: Structure Reports Online, 2013, 69 (2)	en_US
dc.identifier.issn	1600-5368	en_US
dc.identifier.uri	http://hdl.handle.net/10453/116946
dc.description.abstract	In the title compound, C30H48BNOP2·0.5H2O, the water molecule is disordered about an inversion centre. Both phosphorus atoms shows distortions in their tetrahedral environments with the cyclohexyl substituents disordered over two orientations in a 0.851 (3):0.149 (3) occupancy ratio. The crystal structure is assembled via O - H⋯O interactions between pairs of phosphininc amide molecules and water molecules, creating hydrogen-bonded dimers with graph-set R 2 4(8) along [001]. Weak C - H⋯O interactions are also observed.	en_US
dc.relation.ispartof	Acta Crystallographica Section E: Structure Reports Online	en_US
dc.relation.isbasedon	10.1107/S1600536813001839	en_US
dc.subject.classification	Inorganic & Nuclear Chemistry	en_US
dc.title	Rac-[2-(Dicyclohexylphosphanyl)phenyl](phenyl)phosphinic diisopropylamide-borane hemihydrate	en_US
dc.type	Journal Article
utslib.citation.volume	2	en_US
utslib.citation.volume	69	en_US
utslib.for	0303 Macromolecular and Materials Chemistry	en_US
utslib.for	0305 Organic Chemistry	en_US
utslib.for	03 Chemical Sciences	en_US
pubs.embargo.period	Not known	en_US
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
utslib.copyright.status	open_access
pubs.issue	2	en_US
pubs.publication-status	Published	en_US
pubs.volume	69	en_US

Abstract:

In the title compound, C30H48BNOP2·0.5H2O, the water molecule is disordered about an inversion centre. Both phosphorus atoms shows distortions in their tetrahedral environments with the cyclohexyl substituents disordered over two orientations in a 0.851 (3):0.149 (3) occupancy ratio. The crystal structure is assembled via O - H⋯O interactions between pairs of phosphininc amide molecules and water molecules, creating hydrogen-bonded dimers with graph-set R 2 4(8) along [001]. Weak C - H⋯O interactions are also observed.

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http://hdl.handle.net/10453/116946