Catena-Poly[[copper(I)-μ-2,6-bis[4-(pyridin-2-yl)thiazol-2-yl]pyridine] hexafluoridophosphate acetonitrile monosolvate] from single-crystal synchrotron data

Xiao, L; Bhadbhade, M; Baker, AT

Catena-Poly[[copper(I)-μ-2,6-bis[4-(pyridin-2-yl)thiazol-2-yl]pyridine] hexafluoridophosphate acetonitrile monosolvate] from single-crystal synchrotron data

Xiao, L Bhadbhade, M Baker, AT

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Publication Type:: Journal Article
Citation:: Acta Crystallographica Section E: Structure Reports Online, 2013, 69 (4)
Issue Date:: 2013-04-01

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Field	Value	Language
dc.contributor.author	Xiao, L	en_US
dc.contributor.author	Bhadbhade, M	en_US
dc.contributor.author	Baker, AT	en_US
dc.date.accessioned	2017-10-02T03:40:43Z
dc.date.available	2017-10-02T03:40:43Z
dc.date.issued	2013-04-01	en_US
dc.identifier.citation	Acta Crystallographica Section E: Structure Reports Online, 2013, 69 (4)	en_US
dc.identifier.issn	1600-5368	en_US
dc.identifier.uri	http://hdl.handle.net/10453/117987
dc.description.abstract	The title complex, {[Cu(C 21 H 13 N 5 S 2 )]PF 6 ·CH 3 CN} n , was formed immediately on adding together a methanol solution containing copper(I) ions and a methanol solution of 2,6-bis[4-(pyridin-2-yl)thiazol-2-yl]pyridine. Crystallographic studies of the complex reveal a coordination polymer with the ligand acting as a bis(bidentate) ligand with the pyridine N atom n ot coordinating a metal centre. The Cu I atom is four-coordinate with approximately tetrahedral stereochemistry: the N 4 donor set is provided by bipyridine-like moieties of the two heterocyclic ligands. Parallel chains of the coordination polymer run along the b-axis direction with the disordered (0.50:0.50 occupancy ratio) PF 6 - anions and acetonitrile solvent molecules located between the chains.	en_US
dc.relation.ispartof	Acta Crystallographica Section E: Structure Reports Online	en_US
dc.relation.isbasedon	10.1107/S1600536813006831	en_US
dc.subject.classification	Inorganic & Nuclear Chemistry	en_US
dc.title	Catena-Poly[[copper(I)-μ-2,6-bis[4-(pyridin-2-yl)thiazol-2-yl]pyridine] hexafluoridophosphate acetonitrile monosolvate] from single-crystal synchrotron data	en_US
dc.type	Journal Article
utslib.citation.volume	4	en_US
utslib.citation.volume	69	en_US
utslib.for	03 Chemical Sciences	en_US
pubs.embargo.period	Not known	en_US
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
utslib.copyright.status	open_access
pubs.declined	2017-10-02T14:40:43.615+1100
pubs.deleted	2017-10-02T14:40:43.615+1100
pubs.issue	4	en_US
pubs.publication-status	Published	en_US
pubs.volume	69	en_US

Abstract:

The title complex, {[Cu(C 21 H 13 N 5 S 2 )]PF 6 ·CH 3 CN} n , was formed immediately on adding together a methanol solution containing copper(I) ions and a methanol solution of 2,6-bis[4-(pyridin-2-yl)thiazol-2-yl]pyridine. Crystallographic studies of the complex reveal a coordination polymer with the ligand acting as a bis(bidentate) ligand with the pyridine N atom n ot coordinating a metal centre. The Cu I atom is four-coordinate with approximately tetrahedral stereochemistry: the N 4 donor set is provided by bipyridine-like moieties of the two heterocyclic ligands. Parallel chains of the coordination polymer run along the b-axis direction with the disordered (0.50:0.50 occupancy ratio) PF 6 - anions and acetonitrile solvent molecules located between the chains.

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http://hdl.handle.net/10453/117987