Insights into N-doping in single-walled carbon nanotubes for enhanced activation of superoxides: A mechanistic study

Duan, X; Ao, Z; Sun, H; Zhou, L; Wang, G; Wang, S

Insights into N-doping in single-walled carbon nanotubes for enhanced activation of superoxides: A mechanistic study

Duan, X Ao, Z

Sun, H Zhou, L Wang, G

Wang, S

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Publication Type:: Journal Article
Citation:: Chemical Communications, 2015, 51 (83), pp. 15249 - 15252
Issue Date:: 2015-08-10

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Field	Value	Language
dc.contributor.author	Duan, X	en_US
dc.contributor.author	Ao, Z https://orcid.org/0000-0003-0333-3727	en_US
dc.contributor.author	Sun, H	en_US
dc.contributor.author	Zhou, L	en_US
dc.contributor.author	Wang, G https://orcid.org/0000-0003-4295-8578	en_US
dc.contributor.author	Wang, S	en_US
dc.date.issued	2015-08-10	en_US
dc.identifier.citation	Chemical Communications, 2015, 51 (83), pp. 15249 - 15252	en_US
dc.identifier.issn	1359-7345	en_US
dc.identifier.uri	http://hdl.handle.net/10453/123359
dc.description.abstract	© The Royal Society of Chemistry 2015. Emerging characteristics upon nitrogen-doping were differentiated in the activation of superoxides over single-walled carbon nanotubes. Both experimental and theoretical studies revealed that enhanced peroxymonosulfate (PMS) activation is ascribed to a nonradical process while persulfate (PS) activation is accelerated via directly oxidizing water, yet hydrogen peroxide (H2O2) activation is inert to N-doping. This study details the first insights into versatile N-doping in carbocatalysis for organic oxidation in sustainable remediation.	en_US
dc.relation.ispartof	Chemical Communications	en_US
dc.relation.isbasedon	10.1039/c5cc05101k	en_US
dc.subject.classification	Organic Chemistry	en_US
dc.title	Insights into N-doping in single-walled carbon nanotubes for enhanced activation of superoxides: A mechanistic study	en_US
dc.type	Journal Article
utslib.citation.volume	83	en_US
utslib.citation.volume	51	en_US
utslib.for	0303 Macromolecular and Materials Chemistry	en_US
utslib.for	0912 Materials Engineering	en_US
utslib.for	03 Chemical Sciences	en_US
pubs.embargo.period	Not known	en_US
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
pubs.organisational-group	/University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
pubs.organisational-group	/University of Technology Sydney/Strength - CCET - Centre for Clean Energy Technology
utslib.copyright.status	closed_access
pubs.issue	83	en_US
pubs.publication-status	Published	en_US
pubs.volume	51	en_US

Abstract:

© The Royal Society of Chemistry 2015. Emerging characteristics upon nitrogen-doping were differentiated in the activation of superoxides over single-walled carbon nanotubes. Both experimental and theoretical studies revealed that enhanced peroxymonosulfate (PMS) activation is ascribed to a nonradical process while persulfate (PS) activation is accelerated via directly oxidizing water, yet hydrogen peroxide (H2O2) activation is inert to N-doping. This study details the first insights into versatile N-doping in carbocatalysis for organic oxidation in sustainable remediation.

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http://hdl.handle.net/10453/123359