Synthesis of sulphonic lanthanum complex based on C-methylcalixresorcinarene and its thermo-oxidative aging resistance for natural rubber
- Publication Type:
- Journal Article
- Plastics, Rubber and Composites, 2017, 46 (6), pp. 251 - 257
- Issue Date:
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© 2017 Institute of Materials, Minerals and Mining. Published by Taylor & Francis on behalf of the Institute. Sulphonic lanthanum complex based on C-methylcalixresorcinarene (CMCR-La) was synthesised for the thermal-oxidative aging resistance of natural rubber. The structure of CMCR-La was confirmed by FT-IR, 13C NMR and element analysis. TG analysis revealed CMCR-La possessed better thermal stability than commercial antioxidant BHT. Accelerated thermal aging tests and oxidation induction time indicated that CMCR-La could obviously improve the thermal-oxidative aging resistance of NR vulcanisates, which was due to multi-phenolic groups, higher molecular weight, the binding and scavenging effect of La ions on free radicals as well as the extra steric hindrance for phenolic groups.
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