Reversible and Sensitive Hg<sup>2+</sup> Detection by a Cell-Permeable Ytterbium Complex
- Publication Type:
- Journal Article
- Citation:
- Inorganic Chemistry, 2018, 57 (1), pp. 120 - 128
- Issue Date:
- 2018-01-02
Closed Access
Filename | Description | Size | |||
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acs.inorgchem.7b02243.pdf | Published Version | 2.92 MB | Adobe PDF |
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Full metadata record
Field | Value | Language |
---|---|---|
dc.contributor.author |
Bao, G |
en_US |
dc.contributor.author | Zha, S | en_US |
dc.contributor.author | Liu, Z | en_US |
dc.contributor.author | Fung, YH | en_US |
dc.contributor.author | Chan, CF | en_US |
dc.contributor.author | Li, H | en_US |
dc.contributor.author | Chu, PH | en_US |
dc.contributor.author |
Jin, D |
en_US |
dc.contributor.author | Tanner, PA | en_US |
dc.contributor.author | Wong, KL | en_US |
dc.date.issued | 2018-01-02 | en_US |
dc.identifier.citation | Inorganic Chemistry, 2018, 57 (1), pp. 120 - 128 | en_US |
dc.identifier.issn | 0020-1669 | en_US |
dc.identifier.uri | http://hdl.handle.net/10453/124769 | |
dc.description.abstract | © 2017 American Chemical Society. A cell-permeable ytterbium complex shows reversible binding with Hg2+ in aqueous solution and in vitroby off-on visible and NIR emission. The fast response and 150 nM sensitivity of Hg2+ detection is based upon FRET and the lanthanide antenna effect. The reversible Hg2+ detection can be performed in vitro, and the binding mechanism is suggested by NMR employing the motif structure in a La complex and by DFT calculations. | en_US |
dc.relation.ispartof | Inorganic Chemistry | en_US |
dc.relation.isbasedon | 10.1021/acs.inorgchem.7b02243 | en_US |
dc.subject.classification | Inorganic & Nuclear Chemistry | en_US |
dc.subject.mesh | Cells, Cultured | en_US |
dc.subject.mesh | Humans | en_US |
dc.subject.mesh | Ytterbium | en_US |
dc.subject.mesh | Mercury | en_US |
dc.subject.mesh | Organometallic Compounds | en_US |
dc.subject.mesh | Cell Survival | en_US |
dc.subject.mesh | Molecular Structure | en_US |
dc.subject.mesh | Quantum Theory | en_US |
dc.title | Reversible and Sensitive Hg<sup>2+</sup> Detection by a Cell-Permeable Ytterbium Complex | en_US |
dc.type | Journal Article | |
utslib.citation.volume | 1 | en_US |
utslib.citation.volume | 57 | en_US |
utslib.for | 0904 Chemical Engineering | en_US |
utslib.for | 0302 Inorganic Chemistry | en_US |
utslib.for | 0306 Physical Chemistry (incl. Structural) | en_US |
utslib.for | 0399 Other Chemical Sciences | en_US |
pubs.embargo.period | Not known | en_US |
pubs.organisational-group | /University of Technology Sydney | |
pubs.organisational-group | /University of Technology Sydney/Faculty of Science | |
pubs.organisational-group | /University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences | |
pubs.organisational-group | /University of Technology Sydney/Strength - IBMD - Initiative for Biomedical Devices | |
pubs.organisational-group | /University of Technology Sydney/Students | |
utslib.copyright.status | closed_access | |
pubs.issue | 1 | en_US |
pubs.publication-status | Published | en_US |
pubs.volume | 57 | en_US |
Abstract:
© 2017 American Chemical Society. A cell-permeable ytterbium complex shows reversible binding with Hg2+ in aqueous solution and in vitroby off-on visible and NIR emission. The fast response and 150 nM sensitivity of Hg2+ detection is based upon FRET and the lanthanide antenna effect. The reversible Hg2+ detection can be performed in vitro, and the binding mechanism is suggested by NMR employing the motif structure in a La complex and by DFT calculations.
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