How Equilibrium Gets Mimicked during Kinetic and Thermodynamic Control in Porphyrin and Phthalocyanine Self-Assembled Monolayers

Reimers, JR

How Equilibrium Gets Mimicked during Kinetic and Thermodynamic Control in Porphyrin and Phthalocyanine Self-Assembled Monolayers

Reimers, JR

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Publication Type:: Journal Article
Citation:: Langmuir, 2018, 34 (1), pp. 18 - 22
Issue Date:: 2018-01-09

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Field	Value	Language
dc.contributor.author	Reimers, JR https://orcid.org/0000-0001-5157-7422	en_US
dc.date.available	2020-05-25T19:09:15Z
dc.date.issued	2018-01-09	en_US
dc.identifier.citation	Langmuir, 2018, 34 (1), pp. 18 - 22	en_US
dc.identifier.issn	0743-7463	en_US
dc.identifier.uri	http://hdl.handle.net/10453/124886
dc.description.abstract	© 2017 American Chemical Society. The recent review of Hipps and Mazur is extended to consider the origins and significance of their conclusion that "surface structures vary with relative component concentration in a way that may mimic equilibria but is not". How this situation can arise during self-assembly is discussed, as well as a range of qualitative and quantitative observations and high-level free-energy calculations that document the effect for meso-tetraalkylporphyrins self-assembled monolayer (SAM) polymorphs. This leads to a discussion of modern challenges facing quantification of the effects caused by kinetic control, as well as to the usefulness of equilibrium mimicking in the design and synthesis of SAMs.	en_US
dc.relation.ispartof	Langmuir	en_US
dc.relation.isbasedon	10.1021/acs.langmuir.7b03320	en_US
dc.subject.classification	Chemical Physics	en_US
dc.subject.mesh	Porphyrins	en_US
dc.subject.mesh	Indoles	en_US
dc.subject.mesh	Membranes, Artificial	en_US
dc.subject.mesh	Kinetics	en_US
dc.subject.mesh	Thermodynamics	en_US
dc.title	How Equilibrium Gets Mimicked during Kinetic and Thermodynamic Control in Porphyrin and Phthalocyanine Self-Assembled Monolayers	en_US
dc.type	Journal Article
utslib.citation.volume	1	en_US
utslib.citation.volume	34	en_US
utslib.for	0306 Physical Chemistry (incl. Structural)	en_US
utslib.for	0202 Atomic, Molecular, Nuclear, Particle and Plasma Physics	en_US
pubs.embargo.period	Not known	en_US
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
pubs.organisational-group	/University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
utslib.copyright.status	open_access
pubs.issue	1	en_US
pubs.publication-status	Published	en_US
pubs.volume	34	en_US

Abstract:

© 2017 American Chemical Society. The recent review of Hipps and Mazur is extended to consider the origins and significance of their conclusion that "surface structures vary with relative component concentration in a way that may mimic equilibria but is not". How this situation can arise during self-assembly is discussed, as well as a range of qualitative and quantitative observations and high-level free-energy calculations that document the effect for meso-tetraalkylporphyrins self-assembled monolayer (SAM) polymorphs. This leads to a discussion of modern challenges facing quantification of the effects caused by kinetic control, as well as to the usefulness of equilibrium mimicking in the design and synthesis of SAMs.

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http://hdl.handle.net/10453/124886