Radiation-Induced Damage and Recovery of Ultra-Nanocrystalline Diamond: Toward Applications in Harsh Environments

Publication Type:
Journal Article
Citation:
ACS Applied Materials and Interfaces, 2017, 9 (45), pp. 39790 - 39794
Issue Date:
2017-11-15
Metrics:
Full metadata record
Files in This Item:
Filename Description Size
acsami.7b12240.pdfPublished Version2.72 MB
Adobe PDF
© 2017 American Chemical Society. Ultra-nanocrystalline diamond (UNCD) is increasingly being used in the fabrication of devices and coatings due to its excellent tribological properties, corrosion resistance, and biocompatibility. Here, we study its response to irradiation with kiloelectronvolt electrons as a controlled model for extreme ionizing environments. Real time Raman spectroscopy reveals that the radiation-damage mechanism entails dehydrogenation of UNCD grain boundaries, and we show that the damage can be recovered by annealing at 883 K. Our results have significant practical implications for the implementation of UNCD in extreme environment applications, and indicate that the films can be used as radiation sensors.
Please use this identifier to cite or link to this item: