Protecting group-free use of alcohols as carbon electrophiles in atom efficient aluminium triflate-catalysed dehydrative nucleophilic displacement reactions

Cullen, A; Muller, AJ; Williams, DBG

Protecting group-free use of alcohols as carbon electrophiles in atom efficient aluminium triflate-catalysed dehydrative nucleophilic displacement reactions

Cullen, A Muller, AJ Williams, DBG

Permalink

Publication Type:: Journal Article
Citation:: RSC Advances, 2017, 7 (67), pp. 42168 - 42171
Issue Date:: 2017-01-01

Open Access

Copyright Clearance Process

Recently Added
In Progress
Open Access

This item is open access.

Adobe PDF

Download Published VersionAdobe PDF (362.15 kB)

View on publisher's site

View statistics

Full metadata record

Field	Value	Language
dc.contributor.author	Cullen, A	en_US
dc.contributor.author	Muller, AJ	en_US
dc.contributor.author	Williams, DBG https://orcid.org/0000-0002-3703-6301	en_US
dc.date.issued	2017-01-01	en_US
dc.identifier.citation	RSC Advances, 2017, 7 (67), pp. 42168 - 42171	en_US
dc.identifier.uri	http://hdl.handle.net/10453/125346
dc.description.abstract	© 2017 The Royal Society of Chemistry. Benzylic and allylic alcohols are rendered electrophilic without chemical modification by the use of aluminium triflate as catalyst. The reaction succeeds with alcohol, thiol, carbon and nitrogen nucleophiles. When phenols are employed as nucleophiles, C-alkylation ensues. An advanced application of the method is demonstrated in the synthesis of 2H-chromenes and their N and S analogues.	en_US
dc.relation.ispartof	RSC Advances	en_US
dc.relation.isbasedon	10.1039/c7ra08784e	en_US
dc.title	Protecting group-free use of alcohols as carbon electrophiles in atom efficient aluminium triflate-catalysed dehydrative nucleophilic displacement reactions	en_US
dc.type	Journal Article
utslib.citation.volume	67	en_US
utslib.citation.volume	7	en_US
utslib.for	0302 Inorganic Chemistry	en_US
utslib.for	03 Chemical Sciences	en_US
pubs.embargo.period	Not known	en_US
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
utslib.copyright.status	open_access
pubs.issue	67	en_US
pubs.publication-status	Published	en_US
pubs.volume	7	en_US

Abstract:

© 2017 The Royal Society of Chemistry. Benzylic and allylic alcohols are rendered electrophilic without chemical modification by the use of aluminium triflate as catalyst. The reaction succeeds with alcohol, thiol, carbon and nitrogen nucleophiles. When phenols are employed as nucleophiles, C-alkylation ensues. An advanced application of the method is demonstrated in the synthesis of 2H-chromenes and their N and S analogues.

Please use this identifier to cite or link to this item:

http://hdl.handle.net/10453/125346