Investigation of nano-sized Cu(II)O as a high capacity conversion material for Li-metal cells and lithium-ion full cells

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Journal Article
Journal of Materials Chemistry A, 2017, 5 (14), pp. 6556 - 6568
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© The Royal Society of Chemistry. In this study, self-prepared nanostructured CuO electrodes show no capacity decay for 40 cycles at 0.1C in Li metal cells. The reaction mechanisms of the CuO electrodes are investigated. With the help of in situ EIS, in situ XRD, TEM, XAS, SQUID, IC and GC-MS, it is found that the as-prepared CuO electrode undergoes significant phase and composition changes during the initial lithiation, with the transformation of CuO to nano-crystalline Cu. During the 1 st delithiation, Cu is inhomogeneously oxidized, which yields a mixture of Cu 2 O, Cu 2−x O and Cu. The incomplete conversion reaction during the 1 st cycle is accompanied by the formation and partial decomposition of the solid electrolyte interphase (SEI) as the side reactions. Nevertheless, from the 1 st to the 5 th delithiation, the oxidation state of Cu approaches +2. After an additional formation step, the transformation to Cu and back to Cu 2−x O remains stable during the subsequent long-term cycling with no electrolyte decomposition products detected. The LiNi 1/3 Mn 1/3 Co 1/3 O 2 (NMC-111)/CuO full cells show high capacities (655.8 ± 0.6, 618.6 ± 0.9 and 290 ± 2 mA h g −1 at 0.1, 1 and 10C, respectively), within the voltage range of 0.7-4.0 V at 20 °C and a high capacity retention (85% after 200 cycles at 1C).
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