Conversion of single crystals of a nickel(II) dithiocarbamate complex to nickel sulfide crystals

Angeloski, A; Cortie, MB; Scott, JA; Bordin, DM; McDonagh, AM

Conversion of single crystals of a nickel(II) dithiocarbamate complex to nickel sulfide crystals

Angeloski, A

Cortie, MB

Scott, JA Bordin, DM McDonagh, AM

Permalink

Publication Type:: Journal Article
Citation:: Inorganica Chimica Acta, 2019, 487 pp. 228 - 233
Issue Date:: 2019-03-01

Open Access

Copyright Clearance Process

Recently Added
In Progress
Open Access

This item is open access.

Adobe PDF

Download Accepted Manuscript VersionAdobe PDF (819.88 kB)

View on publisher's site

View statistics

Full metadata record

Field	Value	Language
dc.contributor.author	Angeloski, A https://orcid.org/0000-0003-4395-1829	en_US
dc.contributor.author	Cortie, MB https://orcid.org/0000-0003-3202-6398	en_US
dc.contributor.author	Scott, JA	en_US
dc.contributor.author	Bordin, DM	en_US
dc.contributor.author	McDonagh, AM https://orcid.org/0000-0002-9502-1175	en_US
dc.date.available	2021-01-01T18:02:37Z
dc.date.issued	2019-03-01	en_US
dc.identifier.citation	Inorganica Chimica Acta, 2019, 487 pp. 228 - 233	en_US
dc.identifier.issn	0020-1693	en_US
dc.identifier.uri	http://hdl.handle.net/10453/129203
dc.description.abstract	© 2018 Elsevier B.V. Single crystals of bis(κ2S,S′-di(isopropyl)dithiocarbamato) nickel(II) were utilized as a single source precursor for the formation of NiS via thermolysis. The complex decomposed at ∼250 °C to form α-NiS exclusively with no β-NiS detected. Analysis of the thermolysis regime using in situ techniques showed that the thermolysis occurs in a single step with the major volatile side-products being isopropyl-isothiocyanate and carbon disulfide. The resultant NiS was examined using SEM and TEM to reveal a retention of precursor crystal edge-length and angle relationships.	en_US
dc.relation.ispartof	Inorganica Chimica Acta	en_US
dc.relation.isbasedon	10.1016/j.ica.2018.12.014	en_US
dc.rights	info:eu-repo/semantics/openAccess
dc.subject.classification	Inorganic & Nuclear Chemistry	en_US
dc.title	Conversion of single crystals of a nickel(II) dithiocarbamate complex to nickel sulfide crystals	en_US
dc.type	Journal Article
utslib.citation.volume	487	en_US
utslib.for	0302 Inorganic Chemistry	en_US
utslib.for	0306 Physical Chemistry (incl. Structural)	en_US
utslib.for	0399 Other Chemical Sciences	en_US
pubs.embargo.period	Not known	en_US
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
pubs.organisational-group	/University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
pubs.organisational-group	/University of Technology Sydney/Strength - CCET - Centre for Clean Energy Technology
utslib.copyright.status	open_access	*
pubs.publication-status	Published	en_US
pubs.volume	487	en_US

Abstract:

© 2018 Elsevier B.V. Single crystals of bis(κ2S,S′-di(isopropyl)dithiocarbamato) nickel(II) were utilized as a single source precursor for the formation of NiS via thermolysis. The complex decomposed at ∼250 °C to form α-NiS exclusively with no β-NiS detected. Analysis of the thermolysis regime using in situ techniques showed that the thermolysis occurs in a single step with the major volatile side-products being isopropyl-isothiocyanate and carbon disulfide. The resultant NiS was examined using SEM and TEM to reveal a retention of precursor crystal edge-length and angle relationships.

Please use this identifier to cite or link to this item:

http://hdl.handle.net/10453/129203