Encapsulation-Free Stabilization of Few-Layer Black Phosphorus

Elbadawi, C; Queralt, RT; Xu, ZQ; Bishop, J; Ahmed, T; Kuriakose, S; Walia, S; Toth, M; Aharonovich, I; Lobo, CJ

Encapsulation-Free Stabilization of Few-Layer Black Phosphorus

Elbadawi, C Queralt, RT Xu, ZQ

Bishop, J

Ahmed, T Kuriakose, S Walia, S Toth, M

Aharonovich, I

Lobo, CJ

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Publication Type:: Journal Article
Citation:: ACS Applied Materials and Interfaces, 2018, 10 (29), pp. 24327 - 24331
Issue Date:: 2018-07-25

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Field	Value	Language
dc.contributor.author	Elbadawi, C	en_US
dc.contributor.author	Queralt, RT	en_US
dc.contributor.author	Xu, ZQ https://orcid.org/0000-0001-7291-1426	en_US
dc.contributor.author	Bishop, J https://orcid.org/0000-0001-6895-7544	en_US
dc.contributor.author	Ahmed, T	en_US
dc.contributor.author	Kuriakose, S	en_US
dc.contributor.author	Walia, S	en_US
dc.contributor.author	Toth, M https://orcid.org/0000-0003-1564-4899	en_US
dc.contributor.author	Aharonovich, I https://orcid.org/0000-0003-4304-3935	en_US
dc.contributor.author	Lobo, CJ https://orcid.org/0000-0002-2746-1363	en_US
dc.date.issued	2018-07-25	en_US
dc.identifier.citation	ACS Applied Materials and Interfaces, 2018, 10 (29), pp. 24327 - 24331	en_US
dc.identifier.issn	1944-8244	en_US
dc.identifier.uri	http://hdl.handle.net/10453/130288
dc.description.abstract	© 2018 American Chemical Society. Under ambient conditions and in H2O and O2 environments, reactive oxygen species (ROS) cause immediate degradation of the mobility of few-layer black phosphorus (FLBP). Here, we show that FLBP degradation can be prevented by maintaining the temperature in the range ∼125-300 °C during ROS exposure. FLBP devices maintained at elevated temperature show no deterioration of electrical conductance, in contrast to the immediate degradation of pristine FLBP held at room temperature. Our results constitute the first demonstration of stable FLBP in the presence of ROS without requiring encapsulation or a protective coating. The stabilization method will enable applications based on the surface properties of intrinsic FLBP.	en_US
dc.relation	http://purl.org/au-research/grants/arc/DP140102721
dc.relation.ispartof	ACS Applied Materials and Interfaces	en_US
dc.relation.isbasedon	10.1021/acsami.8b04180	en_US
dc.subject.classification	Nanoscience & Nanotechnology	en_US
dc.title	Encapsulation-Free Stabilization of Few-Layer Black Phosphorus	en_US
dc.type	Journal Article
utslib.citation.volume	29	en_US
utslib.citation.volume	10	en_US
utslib.for	0904 Chemical Engineering	en_US
utslib.for	0303 Macromolecular and Materials Chemistry	en_US
utslib.for	0306 Physical Chemistry (incl. Structural)	en_US
utslib.for	03 Chemical Sciences	en_US
utslib.for	09 Engineering	en_US
pubs.embargo.period	Not known	en_US
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
pubs.organisational-group	/University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
pubs.organisational-group	/University of Technology Sydney/Strength - IBMD - Initiative for Biomedical Devices
pubs.organisational-group	/University of Technology Sydney/Strength - MTEE - Research Centre Materials and Technology for Energy Efficiency
utslib.copyright.status	closed_access
pubs.issue	29	en_US
pubs.publication-status	Published	en_US
pubs.volume	10	en_US

Abstract:

© 2018 American Chemical Society. Under ambient conditions and in H2O and O2 environments, reactive oxygen species (ROS) cause immediate degradation of the mobility of few-layer black phosphorus (FLBP). Here, we show that FLBP degradation can be prevented by maintaining the temperature in the range ∼125-300 °C during ROS exposure. FLBP devices maintained at elevated temperature show no deterioration of electrical conductance, in contrast to the immediate degradation of pristine FLBP held at room temperature. Our results constitute the first demonstration of stable FLBP in the presence of ROS without requiring encapsulation or a protective coating. The stabilization method will enable applications based on the surface properties of intrinsic FLBP.

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http://hdl.handle.net/10453/130288