MoS<inf>2</inf>-on-MXene Heterostructures as Highly Reversible Anode Materials for Lithium-Ion Batteries

Chen, C; Xie, X; Anasori, B; Sarycheva, A; Makaryan, T; Zhao, M; Urbankowski, P; Miao, L; Jiang, J; Gogotsi, Y

MoS<inf>2</inf>-on-MXene Heterostructures as Highly Reversible Anode Materials for Lithium-Ion Batteries

Chen, C Xie, X

Anasori, B Sarycheva, A Makaryan, T Zhao, M Urbankowski, P Miao, L Jiang, J Gogotsi, Y

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Publication Type:: Journal Article
Citation:: Angewandte Chemie - International Edition, 2018, 57 (7), pp. 1846 - 1850
Issue Date:: 2018-02-12

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Field	Value	Language
dc.contributor.author	Chen, C	en_US
dc.contributor.author	Xie, X https://orcid.org/0000-0002-8670-8397	en_US
dc.contributor.author	Anasori, B	en_US
dc.contributor.author	Sarycheva, A	en_US
dc.contributor.author	Makaryan, T	en_US
dc.contributor.author	Zhao, M	en_US
dc.contributor.author	Urbankowski, P	en_US
dc.contributor.author	Miao, L	en_US
dc.contributor.author	Jiang, J	en_US
dc.contributor.author	Gogotsi, Y	en_US
dc.date.issued	2018-02-12	en_US
dc.identifier.citation	Angewandte Chemie - International Edition, 2018, 57 (7), pp. 1846 - 1850	en_US
dc.identifier.issn	1433-7851	en_US
dc.identifier.uri	http://hdl.handle.net/10453/130725
dc.description.abstract	© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Two-dimensional (2D) heterostructured materials, combining the collective advantages of individual building blocks and synergistic properties, have spurred great interest as a new paradigm in materials science. The family of 2D transition-metal carbides and nitrides, MXenes, has emerged as an attractive platform to construct functional materials with enhanced performance for diverse applications. Here, we synthesized 2D MoS2-on-MXene heterostructures through in situ sulfidation of Mo2TiC2Tx MXene. The computational results show that MoS2-on-MXene heterostructures have metallic properties. Moreover, the presence of MXene leads to enhanced Li and Li2S adsorption during the intercalation and conversion reactions. These characteristics render the as-prepared MoS2-on-MXene heterostructures stable Li-ion storage performance. This work paves the way to use MXene to construct 2D heterostructures for energy storage applications.	en_US
dc.relation.ispartof	Angewandte Chemie - International Edition	en_US
dc.relation.isbasedon	10.1002/anie.201710616	en_US
dc.subject.classification	Organic Chemistry	en_US
dc.title	MoS<inf>2</inf>-on-MXene Heterostructures as Highly Reversible Anode Materials for Lithium-Ion Batteries	en_US
dc.type	Journal Article
utslib.citation.volume	7	en_US
utslib.citation.volume	57	en_US
utslib.for	0303 Macromolecular and Materials Chemistry	en_US
utslib.for	03 Chemical Sciences	en_US
pubs.embargo.period	Not known	en_US
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
pubs.organisational-group	/University of Technology Sydney/Students
utslib.copyright.status	closed_access
pubs.issue	7	en_US
pubs.publication-status	Published	en_US
pubs.volume	57	en_US

Abstract:

© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Two-dimensional (2D) heterostructured materials, combining the collective advantages of individual building blocks and synergistic properties, have spurred great interest as a new paradigm in materials science. The family of 2D transition-metal carbides and nitrides, MXenes, has emerged as an attractive platform to construct functional materials with enhanced performance for diverse applications. Here, we synthesized 2D MoS2-on-MXene heterostructures through in situ sulfidation of Mo2TiC2Tx MXene. The computational results show that MoS2-on-MXene heterostructures have metallic properties. Moreover, the presence of MXene leads to enhanced Li and Li2S adsorption during the intercalation and conversion reactions. These characteristics render the as-prepared MoS2-on-MXene heterostructures stable Li-ion storage performance. This work paves the way to use MXene to construct 2D heterostructures for energy storage applications.

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http://hdl.handle.net/10453/130725