Highly ordered mesoporous cobalt oxide nanostructures: Synthesis, characterisation, magnetic properties, and applications for electrochemical energy devices

Publication Type:
Journal Article
Citation:
Chemistry - A European Journal, 2010, 16 (36), pp. 11020 - 11027
Issue Date:
2010-09-24
Metrics:
Full metadata record
Files in This Item:
Filename Description Size
Thumbnail2009008439OK.pdf642.89 kB
Adobe PDF
Highly ordered mesoporous Co3O4nanostructures were prepared using KIT-6 and SBA-15 silica as hard templates. The structures were confirmed by small angle X-ray diffraction, high resolution transmission electron microscopy, and N2adsorption-desorption isotherm analysis. Both KIT-6 cubic and SBA-15 hexagonal mesoporous Co3O4samples exhibited a low Néel temperature and bulk antiferromagnetic coupling due to geometric confinement of antiferromagnetic order within the nanoparticles. Mesoporous Co3O4electrode materials have demonstrated the high lithium storage capacity of more than 1200 mAhg-1with an excellent cycle life. They also exhibited a high specific capacitance of 370 Fg-1as electrodes in supercapacitors. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Please use this identifier to cite or link to this item: