Chemical Analysis Of The Superatom Model For Sulfur-Stabilized Gold Nanoparticles

Amer Chemical Soc
Publication Type:
Journal Article
Journal of the American Chemical Society, 2010, 132 (24), pp. 8378 - 8384
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The superatom model for nanoparticle structure is shown to be inadequate for the prediction of the thermodynamic stability of gold nanoparticles. The observed large HOMO-LUMO gaps for stable nanoparticles predicted by this model are, for sulfur-stabilize
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