A Systematic Study of Metal Triflates in Catalytic Transformations of Glucose in Water and Methanol: Identifying the Interplay of Brønsted and Lewis Acidity

Bodachivskyi, I; Kuzhiumparambil, U; Williams, DBG

A Systematic Study of Metal Triflates in Catalytic Transformations of Glucose in Water and Methanol: Identifying the Interplay of Brønsted and Lewis Acidity

Bodachivskyi, I

Kuzhiumparambil, U

Williams, DBG

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Publication Type:: Journal Article
Citation:: ChemSusChem, 2019
Issue Date:: 2019-01-01

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Field	Value	Language
dc.contributor.author	Bodachivskyi, I https://orcid.org/0000-0001-5803-4674	en_US
dc.contributor.author	Kuzhiumparambil, U https://orcid.org/0000-0003-0582-6779	en_US
dc.contributor.author	Williams, DBG https://orcid.org/0000-0002-3703-6301	en_US
dc.date.available	2020-08-01T19:07:56Z
dc.date.issued	2019-01-01	en_US
dc.identifier.citation	ChemSusChem, 2019	en_US
dc.identifier.issn	1864-5631	en_US
dc.identifier.uri	http://hdl.handle.net/10453/134598
dc.description.abstract	© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim The specific type of acidity associated with the given metal trifloromethanesulfonates (Brønsted or Lewis acidity) dramatically influences the course of reactions, and it is possible to select for disaccharides, fructose, methyl glucosides, or methyl levulinate. Glucose is transformed into a range of value-added molecules in water and methanol under the action of acidic metal triflates as catalysts, including their analogous Brønsted acid-assisted or Brønsted base-modified systems. A systematic study is presented of a range of metal triflates in methanol and water, pinning down the preferred conditions to select for each product.	en_US
dc.relation.ispartof	ChemSusChem	en_US
dc.relation.isbasedon	10.1002/cssc.201900292	en_US
dc.rights	info:eu-repo/semantics/openAccess
dc.subject.classification	Organic Chemistry	en_US
dc.subject.classification	General Chemistry	en_US
dc.title	A Systematic Study of Metal Triflates in Catalytic Transformations of Glucose in Water and Methanol: Identifying the Interplay of Brønsted and Lewis Acidity	en_US
dc.type	Journal Article
utslib.for	0399 Other Chemical Sciences	en_US
utslib.for	0301 Analytical Chemistry	en_US
utslib.for	0904 Chemical Engineering	en_US
pubs.embargo.period	Not known	en_US
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
pubs.organisational-group	/University of Technology Sydney/Strength - C3 - Climate Change Cluster
utslib.copyright.status	open_access	*
pubs.publication-status	Published	en_US

Abstract:

© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim The specific type of acidity associated with the given metal trifloromethanesulfonates (Brønsted or Lewis acidity) dramatically influences the course of reactions, and it is possible to select for disaccharides, fructose, methyl glucosides, or methyl levulinate. Glucose is transformed into a range of value-added molecules in water and methanol under the action of acidic metal triflates as catalysts, including their analogous Brønsted acid-assisted or Brønsted base-modified systems. A systematic study is presented of a range of metal triflates in methanol and water, pinning down the preferred conditions to select for each product.

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http://hdl.handle.net/10453/134598