An Unusual Mercury(II) Diisopropyldithiocarbamate Coordination Polymer

Angeloski, A; Rawal, A; Bhadbhade, M; Hook, JM; Schurko, RW; McDonagh, AM

An Unusual Mercury(II) Diisopropyldithiocarbamate Coordination Polymer

Angeloski, A

Rawal, A Bhadbhade, M Hook, JM Schurko, RW McDonagh, AM

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Publication Type:: Journal Article
Citation:: Crystal Growth and Design, 2019, 19 (2), pp. 1125 - 1133
Issue Date:: 2019-02-06

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Field	Value	Language
dc.contributor.author	Angeloski, A https://orcid.org/0000-0003-4395-1829	en_US
dc.contributor.author	Rawal, A	en_US
dc.contributor.author	Bhadbhade, M	en_US
dc.contributor.author	Hook, JM	en_US
dc.contributor.author	Schurko, RW	en_US
dc.contributor.author	McDonagh, AM https://orcid.org/0000-0002-9502-1175	en_US
dc.date.available	2020-05-25T19:25:26Z
dc.date.issued	2019-02-06	en_US
dc.identifier.citation	Crystal Growth and Design, 2019, 19 (2), pp. 1125 - 1133	en_US
dc.identifier.issn	1528-7483	en_US
dc.identifier.uri	http://hdl.handle.net/10453/136231
dc.description.abstract	Copyright © 2019 American Chemical Society. A new polymeric mercury(II) diisopropyldithiocarbamate complex was synthesized by the reaction of sodium diisopropyldithiocarbamate with excess HgCl 2 in water. The precise structure of the new compound was determined by single-crystal X-ray diffraction. A similar reaction, using a stoichiometric excess of the ligand, yielded the known monomeric bis(diisopropyldithiocarbamato)mercury(II) complex. The complexes could not be distinguished from each other by their solution-phase NMR spectra or their FTIR spectra. Solid-state NMR spectroscopy ( 199 Hg and 13 C) provided unambiguous data and showed that the monomeric complex and polymeric complex do not interconvert in solution or during crystal growth. Thermogravimetric experiments revealed quite different thermal decomposition behavior between the two compounds.	en_US
dc.relation.ispartof	Crystal Growth and Design	en_US
dc.relation.isbasedon	10.1021/acs.cgd.8b01619	en_US
dc.subject.classification	Inorganic & Nuclear Chemistry	en_US
dc.title	An Unusual Mercury(II) Diisopropyldithiocarbamate Coordination Polymer	en_US
dc.type	Journal Article
utslib.citation.volume	2	en_US
utslib.citation.volume	19	en_US
utslib.for	0306 Physical Chemistry (incl. Structural)	en_US
utslib.for	0912 Materials Engineering	en_US
utslib.for	0302 Inorganic Chemistry	en_US
pubs.embargo.period	Not known	en_US
pubs.organisational-group	/University of Technology Sydney
pubs.organisational-group	/University of Technology Sydney/Faculty of Science
pubs.organisational-group	/University of Technology Sydney/Faculty of Science/School of Mathematical and Physical Sciences
pubs.organisational-group	/University of Technology Sydney/Strength - CCET - Centre for Clean Energy Technology
utslib.copyright.status	open_access
pubs.issue	2	en_US
pubs.publication-status	Published	en_US
pubs.volume	19	en_US

Abstract:

Copyright © 2019 American Chemical Society. A new polymeric mercury(II) diisopropyldithiocarbamate complex was synthesized by the reaction of sodium diisopropyldithiocarbamate with excess HgCl 2 in water. The precise structure of the new compound was determined by single-crystal X-ray diffraction. A similar reaction, using a stoichiometric excess of the ligand, yielded the known monomeric bis(diisopropyldithiocarbamato)mercury(II) complex. The complexes could not be distinguished from each other by their solution-phase NMR spectra or their FTIR spectra. Solid-state NMR spectroscopy ( 199 Hg and 13 C) provided unambiguous data and showed that the monomeric complex and polymeric complex do not interconvert in solution or during crystal growth. Thermogravimetric experiments revealed quite different thermal decomposition behavior between the two compounds.

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http://hdl.handle.net/10453/136231